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Stereoselective synthesis of vancosamine and saccharosamine glycals via tungsten-catalyzed alkynol cycloisomerization.
- William W. Cutchins, F. McDonald
- Chemistry, Medicine
- Organic letters
- 13 February 2002
[reaction: see text] A stereoselective synthesis of the C-3 branched amino glycals of vancosamine and saccharosamine is described that features a tungsten carbonyl catalyzed cycloisomerization of the… Expand