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The synthesis and catalysis in the ring-opening polymerisation (ROP) of ε-caprolactone (ε-CL) of aluminium(iii) and tin(ii) complexes supported by quinoline-based N,N,O-tridentate ligands are reported. Reaction of 8-{RC(O)CH(2)P(Ph(2)) = N}C(9)H(6)N (R = Bu(t), 2; R = Ph, 3) with AlMe(3) gave [Al(Me(2)){OCR = CHP(Ph(2)) = N(8-C(9)H(6)N)}] (R = Bu(t), 4; R =(More)
A series of aluminium iminophosphoranylenamide complexes, [Me(2)Al{N(Ar)C(Ph)=CHP(Ph(2))=N-Ar(1)}] (Ar = Ph, Ar(1) = p-MeC(6)H(4) (9); Ar = Ph, Ar(1) = o-ClC(6)H(4) (10); Ar = Ph, Ar(1) = o-FC(6)H(4) (11); Ar = p-MeC(6)H(4), Ar(1) = o-FC(6)H(4) (12)), were synthesised by the reactions of ArN=C(Ph)CH(2)P(Ph(2))=NAr(1) (5-8) with AlMe(3) in toluene. Similar(More)
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