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In the title compound, [Tb(C(15)H(11)O(2))(3)(C(17)H(18)N(2))], the 7,7-dimethyl-3-(2-pyrid-yl)-5,6,7,8-tetra-hydro-6,8-methano-iso-quin-oline (L(RR)) ligand coordinates to Tb(III) through the two N atoms of the heterocycle. The metal centre is also chelated by three deprotonated 1,3-diphenyl-propane-1,3-dione (dbm) ligands, forming enanti-omerically pure… (More)
In the title mol-ecule, C(7)H(7)N(5)S, the pyridyl and triazole rings form a dihedral angle of 20.07 (6)°. Inter-molecular N-H⋯N hydrogen bonds link the mol-ecules into chains extended in the direction . Further stability is provided by π⋯π stacking inter-actions, indicated by short distances between the centroids of triazole rings [3.480 (5) Å] and… (More)
A unique supramolecular helix assisted by water tetramers is obtained by static evaporation of aqueous solution of a zwitterionic salt, 1,1'-bis(4-carboxylatebenzyl)-4,4'-bipyridinium; spontaneous chiral symmetry breaking occurs in crystallization; interestingly, redox chromism behavior of crystals upon exposure to alcohol atmosphere has been observed.