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The mass spectra of alkanesulfonyl chlorides can be rationalized by loss of a chlorine atom from the molecular ion, followed by loss of SO2 with concomitant alkyl cation formation. The mass spectra… (More)
A new fragmentation process is reported for two benzylic s-disulfones. The proposed fragmentation Scheme is analogous to the Ramberg-Backlund rearrangement of α-halosulfones in aqueous base.
Chlorine is used to cleave and/or oxidize sulphur compounds as a means of furnishing α-polyhalogeno-sulphoxides, sulphinyl chlorides, or sulphonyl chlorides; a new synthesis of chloromethanesulphonyl… (More)
An examination of the chlorination of phenylmethy), diphenylmethyl, and triphenylmethyl methylsulfonyl sulfides (1, 2, and 3) in aqueous acetic acid has provided indirect evidence for Pummerer… (More)
A series of γ-sulfone sulfonyl chlorides undergo a novel reduction upon reaction with lithium aluminum hydride to furnish the corresponding ethyl sulfones. The reactions appear to proceed in an SN2… (More)
W. R. HARDSTAFF, R. F. LANGLER, J. LEAHY, and M. J. NEWMAN. Can. J. Chem. 53,2664 (1975). An examination of the chlorination of phenylmethyl, diphenylmethyl, and triphenylmethyl methylsulfonyl… (More)
Details are provided of synthetic routes from dialkyl sulfides to both α-halosulfoxides and sulfinyl chlorides. In the case of the former, oxidation of α-halosulfides to the sulfoxide stage is… (More)