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A series of Hoveyda−Grubbs benzylidenes, Ru(X)2(IMesH2)(CH-2-(2-PrO)C6H4) (X = Cl, Br, CF3CO2, C2F5CO2; IMesH2 = 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene) were demonstrated to undergo… (More)
The surface complex [([triple bond]SiO)Re([triple bond]CtBu)(=CHtBu)(CH2tBu)] (1) is a highly efficient propene metathesis catalyst with high initial activities and a good productivity. However, it… (More)
Vacuum-driven anionic ligand exchange of a perfluorocarboxylic acid with ruthenate-bound perfluorocarboxylates is demonstrated and allows for a novel entry to solid-supported ruthenium benzylidenes.