Viktor Bagutski

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Cube-octameric silsesquioxane (POSS) based conjugation scaffolds for copper catalysed azide-alkyne [3+2] cycloaddition are reported. The synthetic route to octaazido and octaalkyno functionalised POSS templates without cage rearrangements is described. A set of click couplings is conducted including the first effective conjugation with a fully unprotected(More)
A useful procedure for the preparation of chemically synthesized and cross-linked polydimethylsiloxane (PDMS) gels is presented, which does not require β-irradiation for cross-linking. NMR spectra of high quality are obtained, such that even mixtures of compounds exhibiting similar NMR spectra like interconverting stereoisomers can be investigated in the(More)
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