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Au36(SPh)24 nanomolecules: X-ray crystal structure, optical spectroscopy, electrochemistry, and theoretical analysis.
- Praneeth Reddy Nimmala, S. Knoppe, V. R. Jupally, J. Delcamp, C. Aikens, A. Dass
- Chemistry, Medicine
- The journal of physical chemistry. B
- 15 October 2014
The physicochemical properties of gold:thiolate nanomolecules depend on their crystal structure and the capping ligands. The effects of protecting ligands on the crystal structure of the… Expand
Ligand dependence of the synthetic approach and chiroptical properties of a magic cluster protected with a bicyclic chiral thiolate.
- S. Knoppe, Nuwan Kothalawala, V. R. Jupally, A. Dass, T. Bürgi
- Chemistry, Medicine
- Chemical communications
- 11 April 2012
Chiral gold clusters stabilised by enantiopure thiolates were prepared, size-selected and characterised by circular dichroism and mass spectrometry. The product distribution is found to be ligand… Expand
Au133(SPh-tBu)52 nanomolecules: X-ray crystallography, optical, electrochemical, and theoretical analysis.
- A. Dass, Shevanuja Theivendran, +7 authors B. Noll
- Chemistry, Medicine
- Journal of the American Chemical Society
- 2 April 2015
Crystal structure determination has revolutionized modern science in biology, chemistry, and physics. However, the difficulty in obtaining periodic crystal lattices which are needed for X-ray crystal… Expand
Interstaple dithiol cross-linking in Au25(SR)18 nanomolecules: a combined mass spectrometric and computational study.
- V. R. Jupally, R. Kota, +4 authors A. Dass
- Chemistry, Medicine
- Journal of the American Chemical Society
- 22 November 2011
A systematic study of cross-linking chemistry of the Au(25)(SR)(18) nanomolecule by dithiols of varying chain length, HS-(CH(2))(n)-SH where n = 2, 3, 4, 5, and 6, is presented here. Monothiolated… Expand
Synthesis of Au130(SR)50 and Au(130-x)Ag(x)(SR)50 nanomolecules through core size conversion of larger metal clusters.
- V. R. Jupally, A. Dass
- Chemistry, Medicine
- Physical chemistry chemical physics : PCCP
- 15 May 2014
Gold nanomolecules with a precise number of metal atoms and thiolate ligands are being used for catalysis, biosensing, drug delivery and as alternative energy sources. Highly monodisperse products,… Expand
Core size conversion: route for exclusive synthesis of Au38 or Au40 nanomolecules.
- Praneeth Reddy Nimmala, V. R. Jupally, A. Dass
- Chemistry, Medicine
- Langmuir : the ACS journal of surfaces and…
- 27 February 2014
Gold nanomolecules with a precise number of gold atoms and ligands have promise for catalytic, optical, and biomedical applications. For practical applications, it is essential to develop synthetic… Expand
Au₁₃₇(SR)₅₆ nanomolecules: composition, optical spectroscopy, electrochemistry and electrocatalytic reduction of CO₂.
- V. R. Jupally, Asantha C. Dharmaratne, +6 authors A. Dass
- Chemistry, Medicine
- Chemical communications
- 31 July 2014
Au137(SR)56, a nanomolecule with a precise number of metal atoms and ligands, was synthesized. The composition was confirmed by MALDI and ESI mass spectrometry using three unique ligands (-SCH2CH2Ph,… Expand
Au103(SR)45, Au104(SR)45, Au104(SR)46 and Au105(SR)46 nanoclusters.
- A. Dass, Praneeth Reddy Nimmala, V. R. Jupally, Nuwan Kothalawala
- Materials Science, Medicine
- Nanoscale
- 22 November 2013
High resolution ESI mass spectrometry of the "22 kDa" nanocluster reveals the presence of a mixture containing Au103(SR)45, Au104(SR)45, Au104(SR)46, and Au105(SR)46 nanoclusters, where R =… Expand
Transformation of Au144(SCH2CH2Ph)60 to Au133(SPh-tBu)52 Nanomolecules: Theoretical and Experimental Study.
- Praneeth Reddy Nimmala, Shevanuja Theivendran, +7 authors A. Dass
- Chemistry, Medicine
- The journal of physical chemistry letters
- 27 May 2015
Ultrastable gold nanomolecule Au144(SCH2CH2Ph)60 upon etching with excess tert-butylbenzenethiol undergoes a core-size conversion and compositional change to form an entirely new core of… Expand
An analysis of the sponge Acanthostrongylophora igens' microbiome yields an actinomycete that produces the natural product manzamine A
- Amanda L. Waters, O. Peraud, +10 authors M. Hamann
- Biology, Medicine
- Front. Mar. Sci.
- 1 October 2014
Sponges have generated significant interest as a source of bioactive and elaborate secondary metabolites that hold promise for the development of novel therapeutics for the control of an array of… Expand