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Salicylic acid dosimetry applied for the statistical determination of significant parameters in a sonochemical reactor
Abstract The effects of operational parameters upon the hydroxyl radical generation of sonochemical reactors are critical to optimize this technology for wastewater treatment purposes. Salicylic acidExpand
Synthesis and biological activity of conformationally constrained sialyl Lewis X analogues with reduced carbohydrate character
Abstract Two conformationally constrained analogues of sialyl Lewis X have been synthesised in which the GlcNAc residue has been replaced with cyclohexyl and phenyl rings. The cyclohexyl derivedExpand
New spiropiperidines as potent and selective non-peptide tachykinin NK2 receptor antagonists.
The synthesis of a series of 2-(5-fluoro-1H-indol-3-yl)ethyl spiropiperidines is described together with their tachykinin NK2 receptor affinities measured in a rat colon binding assay. Equivalent NK2Expand
Mimics of the sialyl Lewis X tetrasaccharide. Replacement of the N-acetylglucosamine sugar with simple C2-symmetric 1,2-diols.
Analogues of sialyl Lewis X have been synthesized that feature replacement of the N-acetylglucosamine residue with C2-symmetric diols. The diols used contain different levels of torsional constraintExpand
Synthesis of a novel analogue of sialyl Lewis X
Abstract Two different strategies have been developed in order to synthesise an analogue and potential mimic of sialyl Lewis X that incorporates a carboxymethyl group and a C 2 -symmetricExpand
Liquid Chromatography-Mass Spectrometry-Based Metabolomics for Understanding the Compositional Changes Induced by Oxidative or Anoxic Storage of Red Wines.
The aim of this work was to study the physicochemical changes of eight red wines stored under conditions differing in O2 exposure and temperature and time under anoxia. The methods used to analyzeExpand
Reactions of carbonyl compounds in basic solutions. Part 13. The mechanism of the alkaline hydrolysis of 3-(3-substituted phenoxy)phthalides, -3-methyl-phthalides, -3-phenylphthalides, naphthalides,
Rate coefficients have been measured for the alkaline hydrolysis of 3-(3-substituted phenoxy)phthalides, -3-methylphthalides, -3-phenylphthalides, naphthalides, -3-phenylnaphthalides, andExpand
Effect of rotation on the reactivity of the D+H2(ν=1)→DH+H system at translational energies 0.25, 0.35 and 0.45 eV
Abstract Quasiclassical trajectory calculations for the D+H2(ν=1)→DH+H reaction have been carried out on the LSTH potential energy surface in the range of translational and rotational energiesExpand