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- Publications
- Influence
Biological Activity and Pharmacological Application of Pectic Polysaccharides: A Review
- S. T. Minzanova, V. Mironov, +4 authors V. Milyukov
- Chemistry, Medicine
- Polymers
- 1 December 2018
Pectin is a polymer with a core of alternating α-1,4-linked d-galacturonic acid and α-1,2-l-rhamnose units, as well as a variety of neutral sugars such as arabinose, galactose, and lesser amounts of… Expand
Organic chemistry of elemental phosphorus
- V. Milyukov, Yu. H. Budnikova, O. Sinyashin
- Chemistry
- 30 September 2005
The principal achievements and the modern trends in the development of the chemistry of elemental phosphorus are analysed, described systematically and generalised. The possibilities and advantages… Expand
Complexation of pectin with macro- and microelements. Antianemic activity of Na, Fe and Na, Ca, Fe complexes.
- S. T. Minzanova, V. Mironov, +6 authors V. Milyukov
- Chemistry, Medicine
- Carbohydrate polymers
- 10 December 2015
New water-soluble pectin complexes with Ca(2+), Mg(2+), Co(2+), Cu(2+), Fe(2+), Mn(2+), Zn(2+) on the basis of pectin biopolymer have been synthesized and successfully tested on white rats. For a… Expand
Trisodium heptaphosphide in reactions with alkyl and aryl tosylates
- V. Milyukov, A. Kataev, E. Hey-Hawkins, O. Sinyashin
- Chemistry
- 1 February 2007
Reactions of trisodium heptaphosphide with alkyl tosylates gave dialkylheptaphosphides or trialkylheptaphosphines, depending on the stoichiometric ratios of the starting reagents. A method for… Expand
Reactions of sodium 3,4,5-triphenyl-1,2-diphosphacyclopentadienide with alkyl halides and silicon and tin chlorides
- V. Milyukov, I. Bezkishko, A. Zagidullin, O. Sinyashin, E. Hey-Hawkins
- Chemistry
- 2 December 2010
Reactions of sodium 3,4,5-triphenyl-1,2-diphosphacyclopentadienide with primary alkyl bromides, secondary alkyl iodides, and silicon and tin chlorides gave stable 1-substituted 1,2-diphospholes. In a… Expand
A new method for the preparation of solution of sodium pentaphosphacyclopentadienide
- V. Milyukov, A. Kataev, O. G. Sinyashin, E. Hey-Hawkins
- Chemistry
- 1 July 2006
Heating of a mixture of white phosphorus and sodium in diethylene glycol dimethyl ether in the presence of catalytic amounts of dibenzo-18-crown-6 affords a pure solution of sodium… Expand
Palladium nanoparticles stabilized by sterically hindered phosphonium salts as Suzuki cross-coupling catalysts
- V. Ermolaev, D. Arkhipova, L. Nigmatullina, I. K. Rizvanov, V. Milyukov, O. Sinyashin
- Chemistry
- Russian Chemical Bulletin
- 1 March 2013
Palladium nanoparticles with an average size of 2.5±0.5 nm formed from palladium acetate in the presence of tri-tert-butyl(decyl)phosphonium tetrafluoroborate without an additional reducing agent… Expand
Cycloaddition reactions of 1-Alkyl-3,4,5-triphenyl-1,2-iphosphacyclopenta-2,4-dienes in the coordination sphere of tungsten carbonyl
- V. Milyukov, A. Zagidullin, E. Hey-Hawkins, O. G. Sinyashin
- Chemistry
- 25 December 2010
Abstract1-Alkyl-3,4,5-triphenyl-1,2-diphosphacyclopenta-2,4-dienes react with tungsten hexacarbonyl under the conditions of “indirect” replacement of the carbonyl group to give 1: 1 complexes; [4+2]… Expand
Synthesis and chemical properties of sodium 3,4,5-tris(diethylamino)-1,2-diphosphacyclopentadienide
- V. Milyukov, L. Shakirova, I. Bezkishko, D. Krivolapov, O. Sinyashin
- Chemistry
- Russian Chemical Bulletin
- 1 July 2012
Abstract1,2,3-Tris(diethylamino)cyclopropenylium iodide (1) reacted with sodium polyphosphides to give sodium 3,4,5-tris(diethylamino)-1,2-diphosphacyclopentadienide (2) in high yields. Chemical… Expand
Reactions of sodium pentaphosphacyclopentadienide with half-sandwich iron complexes
- V. Milyukov, E. Hey-Hawkins, O. G. Sinyashin
- Chemistry
- 1 March 2007
Reactions of sodium pentaphosphacyclopentadienide NaP5 with half-sandwich iron phosphine complexes gave pentaphosphaferrocenes or ferrocenes, depending on the nature and number of substituents in the… Expand