V. Fokin

Publications240
h-index64
Citations28,571
Highly Influential Citations224
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A stepwise huisgen cycloaddition process: copper(I)-catalyzed regioselective "ligation" of azides and terminal alkynes.
  • 8,124
  • 59
Bioconjugation by copper(I)-catalyzed azide-alkyne [3 + 2] cycloaddition.
The copper-catalyzed cycloaddition reaction between azides and alkynes functions efficiently in aqueous solution in the presence of a tris(triazolyl)amine ligand. The process has been employed to… Expand
  • 1,225
  • 16
Polytriazoles as copper(I)-stabilizing ligands in catalysis.
Polytriazolylamines were synthesized by the copper(I)-catalyzed ligation of azides and alkynes. The C3-symmetric derivative, TBTA, was shown to be a powerful stabilizing ligand for copper(I),… Expand
  • 1,012
  • 13
Lipoxin A4 Stable Analogs Are Potent Mimetics That Stimulate Human Monocytes and THP-1 Cells via a G-protein-linked Lipoxin A4 Receptor*
Lipoxins (LX) are bioactive eicosanoids that activate human monocytes and inhibit neutrophils. LXA4 is rapidly converted by monocytes to inactive products, and to resist metabolism, synthetic analogs… Expand
  • 264
  • 12
Polytriazoles as Copper(I)‐Stabilizing Ligands in Catalysis.
  • 137
  • 11
Copper(I)-catalyzed synthesis of azoles. DFT study predicts unprecedented reactivity and intermediates.
Huisgen's 1,3-dipolar cycloadditions become nonconcerted when copper(I) acetylides react with azides and nitrile oxides, providing ready access to 1,4-disubstituted 1,2,3-triazoles and… Expand
  • 1,151
  • 8
Direct Evidence of a Dinuclear Copper Intermediate in Cu(I)-Catalyzed Azide-Alkyne Cycloadditions
How Copper Clicks The copper-catalyzed coupling of azides and alkynes has been termed a “click” reaction on account of its efficiency and versatility, but despite its widespread use, the mechanism… Expand
  • 412
  • 8
Ruthenium-catalyzed cycloaddition of alkynes and organic azides.
Cp*RuCl(PPh3)2 is an effective catalyst for the regioselective "fusion" of organic azides and terminal alkynes, producing 1,5-disubstituted 1,2,3-triazoles. Internal alkynes also participate in this… Expand
  • 123
  • 7
Mechanism of the ligand-free CuI-catalyzed azide-alkyne cycloaddition reaction.
  • 419
  • 6
Copper-Catalyzed Azide—Alkyne Cycloaddition (CuAAC) and Beyond: New Reactivity of Copper(I) Acetylides
  • 72
  • 6
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