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A stepwise huisgen cycloaddition process: copper(I)-catalyzed regioselective "ligation" of azides and terminal alkynes.
- V. Rostovtsev, L. Green, V. Fokin, K. Sharpless
- Chemistry, Medicine
- Angewandte Chemie
- 15 July 2002
Bioconjugation by copper(I)-catalyzed azide-alkyne [3 + 2] cycloaddition.
- Q. Wang, T. Chan, Robert Hilgraf, V. Fokin, K. Sharpless, M. Finn
- Chemistry, Medicine
- Journal of the American Chemical Society
- 22 February 2003
The copper-catalyzed cycloaddition reaction between azides and alkynes functions efficiently in aqueous solution in the presence of a tris(triazolyl)amine ligand. The process has been employed to… Expand
Polytriazoles as copper(I)-stabilizing ligands in catalysis.
- T. Chan, Robert Hilgraf, K. Sharpless, V. Fokin
- Chemistry, Medicine
- Organic letters
- 30 July 2004
Polytriazolylamines were synthesized by the copper(I)-catalyzed ligation of azides and alkynes. The C3-symmetric derivative, TBTA, was shown to be a powerful stabilizing ligand for copper(I),… Expand
Lipoxin A4 Stable Analogs Are Potent Mimetics That Stimulate Human Monocytes and THP-1 Cells via a G-protein-linked Lipoxin A4 Receptor*
- J. Maddox, M. Hachicha, T. Takano, N. Petasis, V. Fokin, C. Serhan
- Biology, Medicine
- The Journal of Biological Chemistry
- 14 March 1997
Lipoxins (LX) are bioactive eicosanoids that activate human monocytes and inhibit neutrophils. LXA4 is rapidly converted by monocytes to inactive products, and to resist metabolism, synthetic analogs… Expand
Polytriazoles as Copper(I)‐Stabilizing Ligands in Catalysis.
- T. Chan, Robert Hilgraf, K. Sharpless, V. Fokin
- Chemistry
- 14 December 2004
Copper(I)-catalyzed synthesis of azoles. DFT study predicts unprecedented reactivity and intermediates.
- F. Himo, T. Lovell, +4 authors V. Fokin
- Chemistry, Medicine
- Journal of the American Chemical Society
- 12 January 2005
Huisgen's 1,3-dipolar cycloadditions become nonconcerted when copper(I) acetylides react with azides and nitrile oxides, providing ready access to 1,4-disubstituted 1,2,3-triazoles and… Expand
Direct Evidence of a Dinuclear Copper Intermediate in Cu(I)-Catalyzed Azide-Alkyne Cycloadditions
- B. Worrell, J. Malik, V. Fokin
- Chemistry, Medicine
- Science
- 26 April 2013
How Copper Clicks The copper-catalyzed coupling of azides and alkynes has been termed a “click” reaction on account of its efficiency and versatility, but despite its widespread use, the mechanism… Expand
Ruthenium-catalyzed cycloaddition of alkynes and organic azides.
- L. Zhang, Xinguo Chen, +5 authors G. Jia
- Chemistry, Medicine
- Journal of the American Chemical Society
- 21 March 2006
Cp*RuCl(PPh3)2 is an effective catalyst for the regioselective "fusion" of organic azides and terminal alkynes, producing 1,5-disubstituted 1,2,3-triazoles. Internal alkynes also participate in this… Expand
Mechanism of the ligand-free CuI-catalyzed azide-alkyne cycloaddition reaction.
- V. Rodionov, V. Fokin, M. Finn
- Chemistry, Medicine
- Angewandte Chemie
- 8 April 2005
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