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Metal-cyclopentadienyl bond dissociation energies (BDEs) were measured for seven metallocene ions (Cp(2)M(+), Cp = η(5)-cyclopentadienyl = c-C(5)H(5), M = Ti, V, Cr, Mn, Fe, Co, Ni) using threshold collision-induced dissociation (TCID) performed in a guided ion beam tandem mass spectrometer. For all seven room temperature metallocene ions, the dominant… (More)