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1H‐nmr studies on the dinucleoside monophosphates containing 2′‐halogeno‐2′‐deoxypurinenucleosides: Effects of 2′‐substitutes on conformation
Seven dinucleoside monophosphates containing 2′‐halogeno‐2′‐deoxypurine nucleoside residue, dAfl‐U, dAcl‐U, dAbr‐U, dAio‐U, dGfl‐U, and dIfl‐C, were chemically synthesized and investigated by 1H‐nmrExpand
  • 6
Synthesis and properties of ApU analogues containing 2'-halo-2'-deoxyadenosines. Effects of 2' substituents on oligonucleotide conformation.
Five A-U analogues containing deoxyadenosine or 2'-halo-2'-deoxyadenosines, which are known to have widely different C3'-endo conformer populations according to their electronegativities of theExpand
  • 11
Improved Synthesis of 2′-Fluoro-2′-Deoxyadenosine and Synthesis and Carbon-13 NMR Spectrum of Its 3′,5′-Cyclic Phosphate Derivative1
Abstract Some improvements were made on synthetic method for 2′-fluoro-2′-deoxyadenosine (11). Thus 11 was obtained in an overall yield of 9.3% starting from adenosine. 2′-Fluoro-2′-deoxyadenosineExpand
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