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The aqueous solution equilibria of a β-lactam antimicrobial agent containing a 3-hydroxy, 4-pyridinone group (L PF) binding to Fe(III) in aqueous solution has been characterized through spectrophotometric and potentiometric titrations. The metal-free ligand has four observable protonation constants, pKa1 = 2.6, pKa2 = 3.43, pKa3 = 6.43, and pKa4 = 9.62. L(More)
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