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The ligand-based quintuple bond-shortening concept and some of its limitations.
Herein, the ligand-based concept of shortening quintuple bonds and some of its limitations are reported. In dichromium-diguanidinato complexes, the length of the quintuple bond can be influenced byExpand
Coordinative Binding of Polymers to Metal-Organic Framework Nanoparticles for Control of Interactions at the Biointerface.
Metal-organic framework nanoparticles (MOF NPs) are of growing interest in diagnostic and therapeutic applications, and due to their hybrid nature, they display enhanced properties compared to moreExpand
Kinetically Controlled Stepwise Self-Assembly of AuI-Metallopeptides in Water.
The combination of attractive supramolecular interactions of a hydrophobic AuI-metallopeptide with the shielding effect of flexible oligoethylene glycol chains provides access to a stepwiseExpand
Cycloaddition reactions of a chromium-chromium quintuple bond.
Bonds with unusually high bond orders have fascinated chemists for nearly half a century. Molecules that have bond orders higher than four have been known for decades. They can be found in transientExpand
Secondary-Structure-Driven Self-Assembly of Reactive Polypept(o)ides: Controlling Size, Shape, and Function of Core Cross-Linked Nanostructures.
Achieving precise control over the morphology and function of polymeric nanostructures during self-assembly remains a challenge in materials as well as biomedical science, especially when independentExpand
Quintuple bond reactivity toward group 16 and 17 elements: addition vs insertion.
The low valent, coordinatively unsaturated, and formally quintuply bonded bimetallic aminopyridinato chromium complex 1 was investigated regarding its reactivity toward group 16 and 17 elements.Expand
CO2 and SO2 activation by a Cr-Cr quintuple bond.
A quintuply bonded dichromium complex stabilized by aminopyridinato ligands activates CO2 and SO2 by reducing the (formal) bond order of the metal-metal bonds. Oxygen abstraction is observed duringExpand
Scandium Aminopyridinates: Synthesis, Structure and Isoprene Polymerization
Alkane elimination reactions of [Sc(CH2SiMe3)3(thf)2] or [Sc(CH2Ph)3(thf)3] with aminopyridines (1a = (2,6-diisopropylphenyl)-[6-(2,4,6-triisopropylphenyl)pyridin-2-yl]amine,1b =Expand
An efficient yttrium catalysed version of the "Aufbaureaktion" for the synthesis of terminal functionalised polyethylene.
The cationic lanthanoid alkyl complexes (NCN)YR(THF)(+) (R = CH(2)SiMe(3)) bearing a NCN-ligand based on N,N'-bis(2,6-diisopropylphenyl)-benzamidine (AmH),Expand
Lanthanoid-transition-metal bonding in bismetallocenes.
Bismetallocenes [Cp2 LuReCp2 ] and [Cp*2 LaReCp2 ] (Cp=cyclopentadienyl; Cp*=pentamethylcyclopentadienyl) were prepared using different synthetic strategies. Salt metathesis-performed in aromaticExpand