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Alkynyliodonium salts in organic synthesis. Application to the total synthesis of the tropoloisoquinoline alkaloid pareitropone.
- K. Feldman, Timothy D. Cutarelli
- Chemistry, Medicine
- Journal of the American Chemical Society
- 4 September 2002
The synthesis of the tropoloisoquinoline alkaloid pareitropone has been accomplished in 14 steps from 2,3,4-trimethoxybenzoic acid. The key transformations include the generation of an… Expand
Total synthesis of the tropoloisoquinoline alkaloid pareitropone via alkynyliodonium salt chemistry and related studies.
- K. Feldman, Timothy D. Cutarelli, Romina Di Florio
- Chemistry, Medicine
- The Journal of organic chemistry
- 2 November 2002
The first chemical synthesis of pareitropone, by a route featuring application of alkynyliodonium salt chemistry, is described. The key transform initiates with addition of an alkylidenecarbene,… Expand
Definition of Several Control Elements Relevant to the Stereodefined Serial Elaboration of Belted Poly(spirotetrahydrofurans) Fitted with a Cyclohexane Core.
- L. Paquette, M. Stepanian, U. V. Mallavadhani, Timothy D. Cutarelli, T. Lowinger, Horst Jan Klemeyer
- Chemistry, Medicine
- The Journal of organic chemistry
- 18 October 1996
The stereochemistry of the condensations of 2-cyclohexenones, alpha-arylidenecyclohexanones, and alpha-(tert-butyldimethylsiloxy)cyclohexanones carrying one or two (both syn and anti)… Expand