Thiruvengadam Munisamy

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The redox properties of [HIPTN(3)N]Mo complexes (where HIPTN(3)N = (3,5-(2,4,6-i-Pr(3)C(6)H(2))(2)C(6)H(3)NCH(2)CH(2))(3)N) involved in the catalytic dinitrogen reduction cycle were studied using cyclic voltammetry in fluorobenzene with Bu(4)NPF(6) as the electrolyte. MoN(2) (Mo = [HIPTN(3)N]Mo, E(1/2) = -1.96 V vs. Fc(+)/Fc at a Pt electrode), Mo≡N (E(1/2)(More)
Electrodeposition of Si on substrates such as Ni, Ag and GC from acetonitrile and tetrahydrofuran containing SiCl4 and SiHCl3 as precursors is reported. The deposits readily oxidize on exposure to air but XPS analysis of a deposit withminimum contact with air confirms that elemental Si (2p, 99.5 eV) is electrodeposited. The deposits contained C, O, N and Cl(More)
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