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The bis(oxazolinyl)-3,5-dimethylphenylrhodium and -iridium complexes were synthesized in high yields by an efficient C-H bond activation method with 4,6-dimethyl-1,3-bis(oxazolinyl)benzene… (More)
The intermolecular reductive coupling reaction of cyclopent-2-enone and aromatic aldehydes was realized by chiral rhodium-(bisoxazolinyl)phenyl catalysts, Rh(Phebox-Ph)(OAc)(2)(H(2)O), with… (More)
A new class of phenyl-bis(oxazoline) auxiliaries was readily prepared from iso- phthaloyl chloride and appropriate β-amino alcohols, and the derived rhodium complexes underwent new cyclization… (More)
Transition metal-catalyzed conjugate reductions of α,β-unsaturated carbonyl compounds mediated by hydride sources, such as hydrosilanes or molecular hydrogen, enable in-situ generation of transition… (More)
Electronic effects of the substituents on the phenyl ring of the phenyl(bisoxazoline) ligand skeleton of rhodium catalysts was examined in the asymmetric reductive aldol reactions of acrylates and… (More)
New asymmetric conjugate reduction of beta,beta-disubstituted alpha,beta-unsaturated ketones and esters was accomplished with alkoxylhydrosilanes in the presence of chiral… (More)