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N-(Triisopropylsilyl)pyrrole. A progenitor "par excellence" of 3-substituted pyrroles
A most useful strategy has been devised for the synthesis of 3-substituted pyrroles on the basis of the kinetic electrophilic substitution of 1-(triisopropylsilyl) pyrrole (1) at the β position and… Expand
Acid-catalyzed enolization and aldol condensation of acetaldehyde
FRET quenching of photosensitizer singlet oxygen generation.
- J. Lovell, Juan Chen, +6 authors G. Zheng
- Chemistry, Medicine
- The journal of physical chemistry. B
- 12 February 2009
The presented findings show that FRET-based quenchers can potently decrease singlet oxygen production and therefore be used to facilitate the rational design of activatable photosensitizers. Expand
Oxidation of Alcohols to Carbonyl Compounds via Alkoxysulfonium Ylides: The Moffatt, Swern, and Related Oxidations
- T. Tidwell
- 15 October 2004
The use of dimethyl sulfoxide as an oxidizing agent began with the discoveries by Kornblum and co-workers that certain α-bromo ketones were converted into glyoxals under mild conditions by treatment… Expand
N-pyrrolylketene: a nonconjugated heteroarylketene.
Ketene 5 is generated from N-pyrrolylacetic acid with use of Mukaiyama's reagent, and reacts with imines forming β-lactams 10, with a product ratio correlation of log(cis/trans) with σ(+). Expand
Kinetic study of the reversible formation of cyclic hemiacetals from 2-(hydroxymethyl)benzaldehyde and 2-(.beta.-hydroxyethyl)benzaldehyde
Hydrodeoxygenation of Hydroxy, Methoxy, and Methyl Phenols with Molybdenum Oxide / Nickel Oxide / Alumina Catalyst
ACID-CATALYZED ENOLIZATION AND ALDOL CONDENSATION OF ACETALDEHYDE
Oxidation of Alcohols by Activated Dimethyl Sulfoxide and Related Reactions: An Update
- T. Tidwell
The current review is intended to emphasize the most important developments in the use of activated DMSO for the oxidation of alcohols since 1981 through 1989, but includes sufficient coverage of the… Expand