Alkali Metal Hydridotriphenylborates [(L)M][HBPh3] (M = Li, Na, K): Chemoselective Catalysts for Carbonyl and CO2 Hydroboration.
- D. Mukherjee, Hassan Osseili, T. Spaniol, J. Okuda
- ChemistryJournal of the American Chemical Society
- 16 August 2016
These compounds also catalyze the hydroborative reduction of CO2 to give formoxyborane HCO2Bpin without any over-reduction.
Magnesium hydridotriphenylborate [Mg(thf)6][HBPh3]2: a versatile hydroboration catalyst.
- D. Mukherjee, Satoru Shirase, T. Spaniol, K. Mashima, J. Okuda
- ChemistryChemical Communications
- 1 November 2016
Magnesium bis(hydridotriphenylborate), isolated as a solvent-separated ion pair [Mg(thf)6][HBPh3]2, effectively catalyzed the hydroboration of several unsaturated substrates including CO2.
A hydride-ligated dysprosium single-molecule magnet.
- A. Venugopal, F. Tuna, R. Layfield
- Physics, ChemistryChemical Communications
- 2 January 2013
An experimental and ab initio computational study of an unsymmetrical, hydride-bridged di-dysprosium single-molecule magnet is reported.
Cationic allyl complexes of the rare-earth metals: synthesis, structural characterization, and 1,3-butadiene polymerization catalysis.
- D. Robert, Elise Abinet, T. Spaniol, J. Okuda
- ChemistryChemistry
- 9 November 2009
For 1,3- butadiene polymerization catalysis, the yttrium-based systems were more active than the corresponding lanthanum or neodymium homologues, giving polybutadiene with approximately 90% 1,4-cis stereoselectivity.
Homogeneous ethylene-polymerization catalysts based on alkyl cations of the rare-earth metals: are dicationic mono(alkyl) complexes the active species?
- S. Arndt, T. Spaniol, J. Okuda
- ChemistryAngewandte Chemie
- 27 October 2003
Half‐Sandwich Alkyl and Hydrido Complexes of Yttrium: Convenient Synthesis and Polymerization Catalysis of Polar Monomers
- K. Hultzsch, T. Spaniol, J. Okuda
- Chemistry
- 15 January 1999
Direct preparation of alkyl half-sandwich complexes of the heavier rare earth elements (such as 1) is possible by alkane elimination from the corresponding cyclopentadiene derivative and the trialkyl…
Allyl complexes of scandium: synthesis and structure of neutral, cationic and anionic derivatives.
- S. Standfuss, Elise Abinet, T. Spaniol, J. Okuda
- ChemistryChemical Communications
- 11 October 2011
Neutral, cationic and anionic allyl compounds of scandium contain highly fluxional allyl ligands in solution, whilst in the solid state both η(1)- and η(3)-binding modes are detected.
Zinc hydridotriphenylborates supported by a neutral macrocyclic polyamine.
- D. Mukherjee, A. Wiegand, T. Spaniol, J. Okuda
- ChemistryDalton Transactions
- 15 May 2017
The zinc hydridotriphenylborates and [(L)Zn(TMDS)][HBPh3] were synthesized by BPh3-mediated β-SiH abstraction and salt metathesis with K HBPh3, respectively and catalyzes the hydroboration of polar substrates including CO2.
The allylcalcium monocation: a bridging allyl ligand with a non-bent coordination geometry.
- C. Lichtenberg, Phillip Jochmann, T. Spaniol, J. Okuda
- Chemistry, MedicineAngewandte Chemie
- 14 June 2011
Oxygen Atom Transfer Reactions with Molybdenum Cofactor Model Complexes That Contain a Tetradentate OSSO-Type Bis(phenolato) Ligand
- T. Schindler, Andreas Sauer, T. Spaniol, J. Okuda
- ChemistryOrganometallics
- 28 August 2018
The catalytic activity of molybdenum complexes in oxidation state +IV, +V, and +VI stabilized by a tetradentate dithiaalkanediyl-2,2′-bis(phenolato) (OSSO)-type ligand was tested in the oxygen atom…
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