T. Shing

Publications207
h-index26
Citations3,029
Highly Influential Citations13
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Inhibition of glutathione S-transferase M1 by new gabosine analogues is essential for overcoming cisplatin resistance in lung cancer cells.
TLDR
The results of this effort show that the lead 4-O-decyl-gabosine D has optimum synergetic effect in A549 human lung adenocarcinoma epithelial cell and that this activity involves inhibition of glutathione S-transferase M1, apparently consistent with siRNA-mediated knockdown of GSTM1 gene.
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Efficient and Facile Glycol Cleavage Oxidation Using Improved Silica Gel-Supported Sodium Metaperiodate.
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Glycosidase inhibition by plant alkaloids which are structural analogues of monosaccharides
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Facile, efficient, and enantiospecific syntheses of 1,1'-N-linked pseudodisaccharides as a new class of glycosidase inhibitors.
TLDR
The acetonide blocking groups were shown to be the best hydroxyl protecting groups, compatible with the palladium-catalyzed allylic amination reaction that afforded high yields of the 1,1'-N-linked pseudodisaccharides with a minimum amount of an elimination diene side product.
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First total synthesis of a barnacle hatching factor 8(R) - hydroxy-eicosa-5(Z),9(E),11(Z),14(Z),17(Z)-pentaenoic acid
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Kinetic studies on cyclophellitol analogues--mechanism-based inactivators.
The (1R,6S)- and (1R,2S,6S)-diastereoisomers of cyclophellitol were found to be effective irreversible inactivators of alpha-D-glucosidase and alpha-D-mannosidase, respectively. The…
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Goniobutenolides A and B : serendipitous synthese, relative and absolute configuration
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Synthetic Studies Towards Pentacyclic Quassinoids: Total Synthesis of Unnatural (‐)‐14‐epi‐Samaderine E and Natural (‐)‐Samaderine Y from (S)‐(+)‐Carvone
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Ruthenium-Catalyzed cis-Dihydroxylation of Alkenes: Scope and Limitations.
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Synthesis of Aryl C-Glycosides via Iron-Catalyzed Cross Coupling of Halosugars: Stereoselective Anomeric Arylation of Glycosyl Radicals.
TLDR
The present cross-coupling reaction demonstrates the potential of iron-catalyzed stereo- and chemoselective carbon-carbon bond formation in the synthesis of bioactive compounds of certain structural complexity.
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