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Lanthanides in organic synthesis
  • 137
  • 1
Dihydroboronium derivatives of (S,S)-1,2-bis(t-butylmethylphosphino)ethane as convenient chiral ligand precursors
Dihydroboronium derivatives of (S,S)-1,2-bis(t-butylmethylphosphino)ethane (t-Bu-BisP*) were prepared and used as chiral diphosphine ligand precursors in Rh-catalyzed asymmetric hydrogenation ofExpand
  • 18
  • 1
An air-stable P-chiral phosphine ligand for highly enantioselective transition-metal-catalyzed reactions.
A new P-chiral phosphine ligand, (R,R)-2,3-bis(tert-butylmethylphosphino)quinoxaline, has been prepared by the reaction of enantiomerically pure tert-butylmethylphosphine-borane withExpand
  • 175
Rigid P-chiral phosphine ligands with tert-butylmethylphosphino groups for rhodium-catalyzed asymmetric hydrogenation of functionalized alkenes.
Both enantiomers of 2,3-bis(tert-butylmethylphosphino)quinoxaline (QuinoxP*), 1,2-bis(tert-butylmethylphosphino)benzene (BenzP*), and 1,2-bis(tert-butylmethylphosphino)-4,5-(methylenedioxy)benzeneExpand
  • 138
On the mechanism of stereoselection in Rh-catalyzed asymmetric hydrogenation: a general approach for predicting the sense of enantioselectivity.
This account brings together the recent experimental and computational data on the mechanism of Rh-catalyzed asymmetric hydrogenation of activated double bonds. Two alternative reaction pathwaysExpand
  • 153
Carbon-carbon bond-forming reactions using cerium metal or organocerium(III) reagents
L'amalgame de cerium est un reactif efficace pour la preparation chimioselective d'alcools homoallyliques a partir d'halogenures allyliques et de composes carbonyles. Ce meme reactif est utilise dansExpand
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Methylene-Bridged P-Chiral Diphosphines in Highly Enantioselective Reactions.
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