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Rational design of single-molecule magnets: a supramolecular approach.
  • T. Glaser
  • Chemistry, Medicine
  • Chemical communications
  • 7 January 2011
Since the discovery that Mn(12)OAc acts as a single-molecule magnet (SMM), an increasing number of transition metal complexes have been demonstrated to behave as SMMs. The signature of a SMM is aExpand
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Description of the ground state wave functions of Ni dithiolenes using sulfur K-edge X-ray absorption spectroscopy.
The pterin-dithiolene cofactor is an essential component of the catalytic sites of all molybdoenzymes except nitrogenase. Understanding its bonding to transition metals allows for development ofExpand
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The Electronic Structures of an Isostructural Series of Octahedral Nitrosyliron Complexes {Fe−NO}6,7,8 Elucidated by Mössbauer Spectroscopy
From the reaction of cis-[(cyclam)FeIII(Cl)2]Cl (cyclam = 1,4,8,11-tetraazacyclotetradecane) with hydroxylamine in water the octahedral nitrosyliron complexes trans-[(cyclam)Fe(NO)Cl](ClO4) (1) andExpand
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Electronic structures of active sites in electron transfer metalloproteins: contributions to reactivity
Abstract Many electron transfer centers in biology involve metal complexes, that exhibit unique spectral features. These reflect highly covalent electronic structures, which contribute to theExpand
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Exchange interactions and zero-field splittings in C3-symmetric Mn(III)6Fe(III): using molecular recognition for the construction of a series of high spin complexes based on the triplesalen ligand.
The reaction of the tris(tetradentate) triplesalen ligand H6talen(t-Bu2), which provides three salen-like coordination environments bridged in a meta-phenylene arrangement by a phloroglucinolExpand
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Electronic Structure of Linear Thiophenolate-Bridged Heterotrinuclear Complexes [LFeMFeL]n+ (M = Cr, Co, Fe; n = 1−3): Localized vs Delocalized Models
The reaction of mononuclear [LFeIII] where L represents the trianionic ligand 1,4,7-tris(4-tert-butyl-2-mercaptobenzyl)-1,4,7-triazacyclononane with CrSO4·5H2O, CoCl2·6H2O, or Fe(BF4)2·6H2O andExpand
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Environmental influence on the single-molecule magnet behavior of [Mn(III)6Cr(III)]3+: molecular symmetry versus solid-state effects.
The structural, spectroscopic, and magnetic properties of a series of [Mn(III)(6)Cr(III)](3+) (= [{(talen(t-Bu(2)))Mn(III)(3)}(2){Cr(III)(CN)(6)}](3+)) compounds have been investigated byExpand
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Synthesis and separation of structural isomers of 2(3),9(10),16(17),23(24)-tetrasubstituted phthalocyanines.
The 2(3),9(10),16(17),23(24)-tetrasubstituted metalphthalocyanines 1-7 (M = In, Ni, Zn) were synthesized, as mixtures of four different structural isomers, from the correspondingExpand
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