Sven Ammermann

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In an attempt to synthesize a novel homoleptic complex 3 from 2-methyl-3-phenylquinoxaline 1 and Ir(acac)(3) for application as a triplet emitter in OLEDs (organic light-emitting diodes) no cyclometalation was observed. Instead, an annulation to 1-methyl-4-phenylpyrrolo[1,2-a]quinoxaline 2 was observed. Since pyrroloquinoxalines are potentially bioactive(More)
The title compound, C(28)H(22)N(4), is the unexpected by-product of the reaction of 2-hydroxy-acetophenone and 1,2-diamino-benzene under iodine catalysis, during which a carbon-carbon σ-bond between two quinoxaline units was formed. Although a fully oxidized title compound should sterically be possible, only one quinoxaline ring is fully oxidized while the(More)
We report the design and characterization of three heteroleptic orange-red phosphorescent iridium(III) complexes bearing two 2-(4-fluorophenyl)-3-methyl-quinoxaline (fpmqx) cyclometalated ligands combined with three different ancillary ligands, triazolylpyridine (trz), picolinate (pic), and acetylacetonate (acac). All of these complexes emit an orange to(More)
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