Susumu Tatemoto

We don’t have enough information about this author to calculate their statistics. If you think this is an error let us know.
Learn More
The carbomethoxy substituted dithiolene ligand (L(COOMe)) enabled us to develop a series of new bis(ene-1,2-dithiolato)tungsten complexes including W(IV)O, W(IV)(OSiBuPh(2)), W(VI)O(2), W(VI)O(OSiBuPh(2)) and W(VI)O(S) core structures. By using these tungsten complexes, a systematic study of the terminal monodentate ligand effects has been performed on the(More)
Oxo-sulfido- and oxo-selenido-molybdenum(VI) complexes with an ene-1,2-dithiolate ligand are generated as models of the active sites of molybdenum hydroxylases. The sulfide and selenide groups are highly reactive toward triphenylphosphine in the order of Se > S.
New dioxomolybdenum(VI) complexes, (Et(4)N)(Ph(4)P)[Mo(VI)O(2)(S(2)C(2)(CO(2)Me)(2))(bdt)] (2) and (Et(4)N)(Ph(4)P)[Mo(VI)O(2)(S(2)C(2)(CO(2)Me)(2))(bdtCl(2))](4)(S(2)C(2)(CO(2)Me)(2) = 1,2-dicarbomethoxyethylene-1,2-ditholate, bdt = 1,2-benzenedithiolate, bdtCl(2) = 3,6-dichloro-1,2-benzenedithiolate), that possess at least one ene-1,2-dithiolate ligand(More)
A monooxomolybdenum(VI) model complex for the oxidized active site in the DMSOR family of molybdoenzymes has been synthesized and structurally characterized. The compound was obtained from the desoxomolybdenum(IV) derivative by clean oxygen-atom transfer from an amine N-oxide in a manner similar to that observed in the enzyme. A combination of electronic(More)
  • 1