Suresh Mummadi

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A new approach to intermolecular frustrated Lewis pairs (FLPs) that combines readily available bulky organosuperbases with moderate to weak boron-containing Lewis acids is reported. These so-called "inverse" FLPs are demonstrated to heterolytically cleave dihydrogen, allowing for the isolation and structural characterization of various phosphonium(More)
A series of mono- and binuclear Lewis acid-base complexes of the formulas N[CH2CH2N(Pri)]3P→LA [LA = BH3 (8), Ga(C6F5)3 (10), GaCl3 (11)], LA←N[CH2CH2N(Pri)]3P [LA = Al(C6F5)3 (6a), AlMe3 (6b), AlEt3 (6c), AlBui3 (6d), BF3 (13)], and LA←N[CH2CH2N(Pri)]3P→LA [Lewis acid (LA) = Al(C6F5)3 (7a), AlMe3 (7b), AlEt3 (7c), AlBui3 (7d), AlCl3 (7e), BH3 (9)] were(More)
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