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Stereoselective glycosylation of d-galactals by diethyl phosphorochloridite- and AlCl3-assisted Ferrier rearrangement
α-2,3-Unsaturated galactosides were synthesized in good to excellent yields by the initial activation of d-galactals with diethyl phosphorochloridite and the subsequent glycosyl addition via FerrierExpand
Separation of structurally similar nocathiacin analogues by reversed phase chromatography.
TLDR
A simple and effective chromatographic method to separate and purify nocathiacin acid from its structural analogue nocATHiacin I was developed and offers a new methodology for the separation of structurally closely related secondary metabolites. Expand