Soumendra K Roy

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A tight-binding model comprising a hopping and an attractive interaction term was considered for high temperature superconductors. Explicit calculations on the effects of isotopic substitution of atoms and application of pressure on the transition temperatures were made in this work. Exact analytical expressions for the isotope-shift exponent (α) and(More)
The observation of the gaseous UFO(-) anion is reported, which is investigated using photoelectron spectroscopy and relativisitic ab initio calculations. Two strong photoelectron bands are observed at low binding energies due to electron detachment from the U-7sσ orbital. Numerous weak detachment bands are also observed due to the strongly correlated U-5f(More)
Herein, an experimental study of the vibrational spectra of HCeN was carried out in solid argon, followed by theoretical investigations of molecular structures and the nature of Ce[triple bond, length as m-dash]N bond. The absorption band at 937.7 cm-1 with the 1.0311 14N/15N isotopic shift ratio is characteristic of Ce[triple bond, length as m-dash]N(More)
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