Someshwar Pola

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Heteroaromatic oligomer 5,7,12,14-tetrachloro-6,13-diazapentacene (TCDAP) was characterized and assessed as n-channel material in field-effect transistor applications. A single-crystal transistor based on TCDAP as the channel material exhibits a very high electron mobility of 3.39 cm(2) V(-1) s(-1) and an on/off ratio of ∼1.08 × 10(4) respectively.
Complexes of cobalt(II), nickel(II), copper(II) and zinc(II) with a new tetraaza macrocyclic ligand have been synthesized and characterized by microanalyses, molar conductance, magnetic susceptibility, mass, thermogravimetric (TGA), IR, 1H and 13C NMR, electronic and ESR spectral studies. All the complexes are found to have the formula [MLX2]x nH2O and are(More)
In this perspective article, we discuss the dynamic instability of charge carrier transport in a range of popular organic semiconductors. We observe that in many cases field-effect mobility, an important parameter used to characterize the performance of organic field-effect transistors (OFETs), strongly depends on the rate of the gate voltage sweep during(More)
A series of disubstituted pyridine derivatives was synthesized from the corresponding acryloyl azides by acetic acid-promoted cycloaddition. This represents a novel and convenient synthetic approach to the symmetric 3,5-disubstituted pyridines. The nature of the substituent on the double bond and the utilized solvent were found to be crucial to the yield of(More)
Nano sized defect pyrochlore, KAl0.33W1.67O6 (KAW), is prepared through sol-gel method. Divalent tin-doped KAW is obtained at room temperature by ion exchange method using acidified SnCl2 and parent KAW. These materials are characterized by powder X-ray diffraction, thermogravimetric analysis (TGA), scanning electron microscopy-energy dispersive spectra(More)
Two compounds (trans-1R,3R-chrysanthemyl R-2-methylbutanoate and R-lavandulyl R-2-methylbutanoate) identified from aeration extracts of virgin female Madeira mealybug, Phenacoccus madeirensis Green (Hemiptera: Pseudococcidae), were synthesized and tested in field bioassays in northern Taiwan over a 1-mo period. In total, 1,492 male P. madeirensis were(More)
Single-crystal field-effect transistors based on 2,3-dimethylpentacene have been used to probe the effect of surface modification of the insulating dielectric SiO(2) layer on the transistor characteristics. Self-assembled monolayers (SAMs) of different chain lengths and functional groups were used to systematically modify the structure and property of the(More)
Here, we report the synthesis and characterization of a series of contorted, yet noncentrosymmetrical, polycyclic aromatic hydrocarbons with a pentabenzo-fused coronene as the core framework. The parent pentabenzo[a,d,g,j,m]coronene (PBC) compound is shown to exhibit a shifted and rotated type of π-π stacking interactions, which render this series a(More)
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