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Functional expression of single-chain variable fragment antibody against c-Met in the cytoplasm of Escherichia coli.

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Enhanced Charge-Transfer Kinetics by Anion Surface Modification of LiFePO4

Despite the great achievement in understanding the materials properties and powder engineering of LiFePO4, the chemical bonding at the surface has been almost ignored. Herein, we demonstrate that the…
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Aggregation-induced emission of diarylamino-π-carborane triads: effects of charge transfer and π-conjugation.

The density functional theory calculations showed that the change in electron distribution between the aryl amino group and the carborane moiety indicates the intramolecular CT character, and the emission colour changes were attributed to the HOMO-LUMO energy gap controlled by the π-extension of the phenylene linker.
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Improving the productivity of recombinant protein in Escherichia coli under thermal stress by coexpressing GroELS chaperone system.

Here, we demonstrate that the overexpression of the GroELS chaperone system, which assists the folding of intracellular proteins and prevents aggregation of its biological targets, can enhance the…
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Highly Selective and Durable Photochemical CO2 Reduction by Molecular Mn(I) Catalyst Fixed on a Particular Dye-Sensitized TiO2 Platform

A Mn(I)-based hybrid system (OrgD-|TiO2|-MnP) for photocatalytic CO2 reduction is designed to be a coassembly of Mn(4,4′-Y2-bpy)(CO)3Br (MnP; Y = CH2PO(OH)2) and…
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Intriguing emission properties of triphenylamine-carborane systems.

Electron donor-acceptor (D-A) systems with a triphenylamino moiety (D) and ortho-carborane (A) show three kinds of intriguing emissions that can be attributed to the local excited state, the…
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Direct observation of the photoinduced electron transfer processes of bis(4-arylphenylamino benzo)-ortho-carborane using transient absorption spectroscopic measurements.

The intramolecular photoinduced electron transfer (PET) processes of three bis(4-arylphenylamino benzo)-ortho-carboranes triads were investigated in CH2Cl2 and n-hexane using the femtosecond time-resolved transient absorption (TA) spectroscopic technique.
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Utility of Squaraine Dyes for Dye-Sensitized Photocatalysis on Water or Carbon Dioxide Reduction

Red light-sensitized squaraine (SQ) dyes were developed and incorporated into dye-sensitized catalysts (DSCs) with the formula of SQ/TiO2/Cat, and their efficacies were evaluated in terms of…
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Influence of π-conjugation structural changes on intramolecular charge transfer and photoinduced electron transfer in donor-π-acceptor dyads.

The PET and ICT processes are strongly influenced by the π-conjugation properties and their mechanisms are also affected by whether selective excitation of the donor or acceptor moiety occurs, which can affect the dynamics and mechanisms for the electron (or charge) transfer.
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Photosensitization Behavior of Ir(III) Complexes in Selective Reduction of CO2 by Re(I)-Complex-Anchored TiO2 Hybrid Catalyst.

A series of cationic Ir(III) complexes ([Ir(btp)2(bpy-X2)]+ (Ir-X+: btp = (2-pyridyl)benzo[b]thiophen-3-yl; bpy-X2 = 4,4'-X2-2,2'-bipyridine (X = OMe, tBu, Me, H, and CN)) were applied as…
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