Silvia Sonzini

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Chiral macromolecules have been widely used as synthetic pockets to mimic natural enzymes and promote asymmetric reactions. An achiral host, cucurbit[8]uril (CB[8]), was used for an asymmetric Lewis acid catalyzed Diels-Alder reaction. We achieved a remarkable increase in enantioselectivity and a large rate acceleration in the presence of the nanoreactor by(More)
All amino acids used, hydroxybenzotriazole (HOBt), dichloromethane (DCM), dimethyl for-mamide (DMF) and 20% piperidine in DMF solution were bought from AGTC Bioproducts and used without further purication. NovaPEG Rink amide LL resin and-aminohexanoic acid (Ahx) were purchased from Merck Novabiochem. Diisopropylcarbodiimide (DIC), diiso-propylethyl-amine(More)
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