Shuping Huang

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Free standing MnSb2S4 2D monolayer nanosheets were developed by a simple calcination of the neutral hydrazine molecule bridged chalcogenide, and were found to display a highly efficient and stable activity for photocatalytic hydrogen evolution from water under visible light irradiation (420-730 nm).
Copolymerization with 2,4,6-triaminopyrimidine (TAP) is developed for precise substitution of one nitrogen with carbon atom in the triazine ring of polymeric g-C3N4. Direct incorporation of C4N2 ring from TAP into the network retains the structural features of g-C3N4, but induces the rolling-up of g-C3N4 sheets into tubular configuration. The band gap(More)
A series of new mononuclear and dinuclear copper(i) triphenylphosphine complexes with functionalized 3-(2'-pyrimidinyl)-1,2,4-triazole ligands have been synthesized and characterized, in which functionalized 3-(2'-pyrimidinyl)-1,2,4-triazole adopts neutral mono- and bis-chelating coordination modes and a mono-anionic bis-chelating binding manner due to the(More)
In this paper, a solid complex of cloxacillin sodium (CS) with Zn(II) was prepared by coprecipitation and characterized by UV, fluorescence, IR, and thermal spectra. Furthermore, the nature of the complex has been studied by 1H-NMR and 13C-NMR spectroscopy. The influence of Zn(II) on the combination of CS and calf thymus DNA (CT DNA) was studied using(More)
Three metal-free molecular photosensitizers (S1-S3) featuring a starburst triarylamine donor moiety have been synthesized. They show attractive photocatalytic performance in visible light-driven H2 production from water in their platinized TiO2 composites. A remarkable H2 turnover number (TON) of 10 200 (48 h) was achieved in an S1-anchored system.
The title compound, C14H24N2O4, is an intermediate in the synthesis of the corresponding heterocyclic compounds. The molecule lies about a twofold axis and has a 'twist' conformation; it adopts the Z,Z configuration, which is shown to be governed mainly by intramolecular hydrogen bonds.
A novel silyl-linked amidinate-amidine monoanionic ligand 3 was synthesized by double additions of PhCN starting from silyl-linked bis(amino) monoanion 2, which underwent an intramolecular Li/H metathesis and double silyl shift. The related Zr(IV) complex 4 was prepared and confirmed by X-ray diffraction revealing a structural rearrangement from its(More)
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