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Journals and Conferences
Measurements of concentrations, size distributions, and vapor-to-particle partitioning for n-alkanes in ambient aerosols were made in the Nagoyaurban area. The average concentration of total particulate n-alkanes in the winter was roughly 5 times higher than that in the summer. The distribution profiles of particulate n-alkanes in the summer showed a… (More)
Dihydrosilanes undergo double trans-hydrosilylation with 1,4-diarylbuta-1,3-diynes in the presence of a cationic ruthenium catalyst to afford 2,5-diarylsiloles: in particular, 9-silafluorene is a good hydrosilylating agent to produce spiro-type siloles in good yield.
A CGH construction of a holographic optical element (HOE) for an optical disk head with spot-size detection by means of superimposing two Fresnel zone plates is studied. Optimum parameter values for the ratio of segment to grating pitch (duty) and grating height are clarified from the viewpoint of total light power efficiency in the round trip optical… (More)
Reaction of triethylgermane and alkynes in the presence of a ruthenium catalyst occurred in a trans fashion. The ruthenium-catalyzed trans-hydrogermylation of 1,3-diynes with dihydrogermanes afforded 2,5-disubstituted germoles in good yield through a two fold addition process. The hydrogermylation reaction was successfully applied to synthesis of… (More)
[reaction: see text] Silicon-bridged 1,6-diynes underwent [2 + 2 + 2] cycloaddition with alkynes in the presence of an iridium(I)-phosphine catalyst to afford densely substituted silafluorene derivatives. Extended silafluorene skeletons were constructed by the [2 + 2 + 2] cycloaddition of tetraynes.
A ring-closing metathesis reaction of allenynes occurred at room temperature in the presence of a molybdenum alkylidene complex to give ring-closed vinylallenes. The vinylallene skeletons were constructed by a metathesis-type reaction between the alkyne moiety and the proximal carbon-carbon double bond of the allene moiety. [reaction: see text]
Two structurally distinct carbocycles were selectively obtained by the reactions of 2-(o-styryl)cyclobutanones promoted by ytterbium salts. Treatment of the cyclobutanones with YbCl(3) in 1,4-dioxane at 100 degrees C afforded 2-(2-chloroethyl)naphthalenes. On the other hand, the reaction with Yb(OTf)(3) in chlorobenzene at 130 degrees C gave… (More)
The best configuration for holographic optical heads for compact disk players is discussed from the viewpoint of considering the misalignment allowance for head components. Focus-error and trackingerror signals of the proposed head configurations are simulated with a ray-tracing method and by using optical cross transfer function theory. The misalignment… (More)
The body-force effect on the lateral movement of cellular flames is studied by unsteady calculations of reactive flows at low Lewis numbers. We employ the compressible Navier-Stokes equation including chemical reaction to take account of the hydrodynamic effect caused by thermal expansion. A sinusoidal disturbance with the linearly most unstable wavelength… (More)
3-Allyl-1-silaindenes are synthesised from alkynes having an allylsilane moiety by a gold-catalysed intramolecular trans-allylsilylation reaction.