Shin-ichiro Ishida

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[28]Hexaphyrin GeIV and SnIV complexes were synthesized in high yields by reactions of [28]hexaphyrin with GeCl4 or SnCl4 in the presence of triethylamine. Both complexes display distinct 28π Möbius aromatic character and possess a trigonal bipyramidal geometry at the central GeIV or SnIV atom. The equatorial hydroxy group of the GeIV complex was smoothly(More)
Protonation of meso-aryl [28]hexaphyrins(1.1.1.1.1.1) triggered conformational changes. Whereas protonation with trifluoroacetic acid led to the formation of monoprotonated Möbius aromatic species, protonation with methanesulfonic acid led to the formation of diprotonated triangular antiaromatic species. A peripherally hexaphenylated [28]hexaphyrin was(More)
Incorporation of Si(IV) into an expanded porphyrin has been achieved for the first time. Treatment of [28]hexaphyrin 1 with CH(3)SiCl(3) and N,N-diisopropylethylamine gave Si(IV) complex 2 and its N-fused product 4 that both have Möbius aromatic nature. In both complexes, the coordinated Si atom is satisfied in a typical trigonal bipyramidal coordination.(More)
Herein, the synthesis of Möbius aromatic [28]hexaphyrin silicon complexes bearing various Si-substituents from reactions of [28]hexaphyrin 1 with suitable silicon sources in the presence of a base is reported. Si-substituents newly introduced are vinyl (4), phenyl (6), hydroxy (7), and hydride groups (8). X-ray crystallographic analysis of complexes 6 and 7(More)
Treatment of nonaromatic N-fused [24]pentaphyrin with trichloromethylsilane in the presence of a base afforded doubly N-fused [24]pentaphyrin and its silicon complex. Addition of fluoride ion to the silicon complex led to the formation of its fluorosilicate as an unprecedented monoanionic six-coordinated Si(IV) complex of porphyrinoid. Treatment of the(More)
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