Shin Hye Ahn

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The di(hydroperoxy)alkane adducts of phosphine oxides 1-9, Ph3 PO⋅(HOO)2 CMe2 , Cy3 PO⋅(HOO)2 CMe2 , Ph3 PO⋅ (HOO)2 CMeEt, Cy3 PO⋅(HOO)2 CMeEt, Cy3 PO⋅(HOO)2 CEt2 , Cy3 PO⋅ (HOO)2 C(CH2 )5 , Cy3 PO⋅(HOO)2 CMePh, (Ph2 P(O)CH2 CH2 P(O)Ph2 )⋅ ((HOO)2 CEt2 )2 , and Ph2 P(O)CH2 P(O)Ph2 ⋅(HOO)2 CMe2 , respectively, are synthesized and fully characterized by 1 H,(More)
Aqueous hydrogen peroxide is widely used as an oxidizing agent in industry and academia. Herein, the hydrogen peroxide adducts of phosphine oxides, [tBu3PO⋅H2O2]2 and [Ph3PO⋅H2O2]2⋅H2O2, are described. Additionally, the corresponding di(hydroperoxy)propane adducts R3PO⋅(HOO)2CMe2 (R=Cy, Ph) were synthesized and characterized. All adducts could be obtained(More)
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