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An Analysis of the Single-Stage Tympanoplasty With Over–Underlay Grafting in Tympanosclerosis

Second-stage surgery for stapedectomy and placement of a prosthesis-like piston or total ossicular replacement prosthesis should be considered to obtain better hearing results in tympanosclerosis.
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Tunable LiCl@UiO-66 composites for water sorption-based heat transformation applications

Porous composite materials are potential candidates for water-based adsorptive heat transformation (AHT) applications. Here, a solid adsorbent LiCl@UiO-66 as a 'composite salt inside porous matrix’…
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Air-Con Metal–Organic Frameworks in Binder Composites for Water Adsorption Heat Transformation Systems

Metal–organic frameworks (MOFs) currently receive high interest for cycling water adsorption applications like adsorption heat transformation for air-conditioning purposes. For practical use in…
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Environmentally benign dry-gel conversions of Zr-based UiO metal-organic frameworks with high yield and the possibility of solvent re-use.

It is shown that solvent re-use is possible over at least five synthesis runs making the DGC method an ecological and extremely solvent-economical route to obtain Zr-based UiO-MOFs with reproducible results.
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Realizing the Potential of Acetylenedicarboxylate by Functionalization to Halofumarate in ZrIV Metal-Organic Frameworks.

The acetylenedicarboxylate linker and its functionalizable triple-bond discloses its potential in the engineering of microporous materials with targeted properties.
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Microwave-assisted dry-gel conversion-a new sustainable route for the rapid synthesis of metal-organic frameworks with solvent re-use.

Microwave-assisted dry-gel conversion allows for the recovery and re-use of the reaction solvent and thereby can significantly reduce the overall solvent waste in the syntheses of the four important MOFs MIL-100(Fe) (Basolite F300), UiO-66, MIL-140A and aluminium fumarate (Alfum, Basolite A520).
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rtl-M-MOFs (M = Cu, Zn) with a T-shaped bifunctional pyrazole-isophthalate ligand showing flexibility and S-shaped Type F-IV sorption isotherms with high saturation uptakes for M = Cu.

Two new rtl-MOFs have been synthesized by using the new bifunctional ligand 5-(4-(3,5-dimethyl-1H-pyrazolyl)azo)isophthalic acid (H3Isa-az-dmpz) and both frameworks are potentially porous structures with DMF molecules included in the channels of the as synthesized materials.
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The Complexity of Comparative Adsorption of C6 Hydrocarbons (Benzene, Cyclohexane, n-Hexane) at Metal–Organic Frameworks

The relatively stable MOFs Alfum, MIL-160, DUT-4, DUT-5, MIL-53-TDC, MIL-53, UiO-66, UiO-66-NH2, UiO-66(F)4, UiO-67, DUT-67, NH2-MIL-125, MIL-125, MIL-101(Cr), ZIF-8, ZIF-11 and ZIF-7 were studied…
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Increase of network hydrophilicity from sql to lvt supramolecular isomers of Cu-MOFs with the bifunctional 4-(3,5-dimethyl-1H-pyrazol-4-yl)benzoate linker.

The bifunctional linker 4-(3,5-dimethyl-1H-pyrazol-4-yl)benzoic acid (H2mpba) was used for the synthesis of new (square lattice) sql 2D metal-organic frameworks (MOFs) in a solvent-mixture of dimethylformamide/water and acetonitrile/water to categorized as hydrophobic materials in contrast to the hydrophilic lvt framework.
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Flexible bifunctional monoethylphosphonate/carboxylates of Zn(ii) and Co(ii) reinforced with DABCO co-ligand: paradigmatic structural organization with pcu topology

Two novel isostructural phosphonate-monoethylcarboxylate MOFs with the structural formula of [M2(EtBCP)2(DABCO)0.5]·2DMA (M = Zn (2), Co (3); H2EtBCP = O-ethyl-P-(4-carboxyphenyl)phosphonic acid,…
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