An Analysis of the Single-Stage Tympanoplasty With Over–Underlay Grafting in Tympanosclerosis
- Y. Bayazıt, E. Ozer, C. Kara, Serkan Gökpinar, M. Kanlıkama, S. Mumbuç
- MedicineOtology and Neurotology
- 1 May 2004
Second-stage surgery for stapedectomy and placement of a prosthesis-like piston or total ossicular replacement prosthesis should be considered to obtain better hearing results in tympanosclerosis.
Tunable LiCl@UiO-66 composites for water sorption-based heat transformation applications
- Yangyang Sun, A. Spieß, C. Janiak
- 7 July 2020
Porous composite materials are potential candidates for water-based adsorptive heat transformation (AHT) applications. Here, a solid adsorbent LiCl@UiO-66 as a 'composite salt inside porous matrix’…
Air-Con Metal–Organic Frameworks in Binder Composites for Water Adsorption Heat Transformation Systems
- Serkan Gökpinar, S. Ernst, C. Janiak
- Materials Science, EngineeringIndustrial & Engineering Chemistry Research
- 24 October 2019
Metal–organic frameworks (MOFs) currently receive high interest for cycling water adsorption applications like adsorption heat transformation for air-conditioning purposes. For practical use in…
Environmentally benign dry-gel conversions of Zr-based UiO metal-organic frameworks with high yield and the possibility of solvent re-use.
- Serkan Gökpinar, T. Diment, C. Janiak
- Materials ScienceDalton Transactions
- 1 August 2017
It is shown that solvent re-use is possible over at least five synthesis runs making the DGC method an ecological and extremely solvent-economical route to obtain Zr-based UiO-MOFs with reproducible results.
Realizing the Potential of Acetylenedicarboxylate by Functionalization to Halofumarate in ZrIV Metal-Organic Frameworks.
- Tobie J Matemb Ma Ntep, H. Reinsch, C. Janiak
- Materials Science, ChemistryChemistry
- 22 August 2018
The acetylenedicarboxylate linker and its functionalizable triple-bond discloses its potential in the engineering of microporous materials with targeted properties.
Microwave-assisted dry-gel conversion-a new sustainable route for the rapid synthesis of metal-organic frameworks with solvent re-use.
- Niels Tannert, Serkan Gökpinar, Emrah Hastürk, S. Nießing, C. Janiak
- Materials ScienceDalton Transactions
- 24 July 2018
Microwave-assisted dry-gel conversion allows for the recovery and re-use of the reaction solvent and thereby can significantly reduce the overall solvent waste in the syntheses of the four important MOFs MIL-100(Fe) (Basolite F300), UiO-66, MIL-140A and aluminium fumarate (Alfum, Basolite A520).
rtl-M-MOFs (M = Cu, Zn) with a T-shaped bifunctional pyrazole-isophthalate ligand showing flexibility and S-shaped Type F-IV sorption isotherms with high saturation uptakes for M = Cu.
- S. Millan, B. Gil-Hernández, C. Janiak
- Materials Science, ChemistryDalton Transactions
- 11 June 2019
Two new rtl-MOFs have been synthesized by using the new bifunctional ligand 5-(4-(3,5-dimethyl-1H-pyrazolyl)azo)isophthalic acid (H3Isa-az-dmpz) and both frameworks are potentially porous structures with DMF molecules included in the channels of the as synthesized materials.
The Complexity of Comparative Adsorption of C6 Hydrocarbons (Benzene, Cyclohexane, n-Hexane) at Metal–Organic Frameworks
- Christian Jansen, Nabil Assahub, C. Janiak
- 1 October 2022
The relatively stable MOFs Alfum, MIL-160, DUT-4, DUT-5, MIL-53-TDC, MIL-53, UiO-66, UiO-66-NH2, UiO-66(F)4, UiO-67, DUT-67, NH2-MIL-125, MIL-125, MIL-101(Cr), ZIF-8, ZIF-11 and ZIF-7 were studied…
Increase of network hydrophilicity from sql to lvt supramolecular isomers of Cu-MOFs with the bifunctional 4-(3,5-dimethyl-1H-pyrazol-4-yl)benzoate linker.
- Saskia Menzel, S. Millan, C. Janiak
- ChemistryDalton Transactions
- 10 September 2020
The bifunctional linker 4-(3,5-dimethyl-1H-pyrazol-4-yl)benzoic acid (H2mpba) was used for the synthesis of new (square lattice) sql 2D metal-organic frameworks (MOFs) in a solvent-mixture of dimethylformamide/water and acetonitrile/water to categorized as hydrophobic materials in contrast to the hydrophilic lvt framework.
Flexible bifunctional monoethylphosphonate/carboxylates of Zn(ii) and Co(ii) reinforced with DABCO co-ligand: paradigmatic structural organization with pcu topology
- Anna Goldman, B. Gil-Hernández, C. Janiak
- Materials Science
- 4 May 2020
Two novel isostructural phosphonate-monoethylcarboxylate MOFs with the structural formula of [M2(EtBCP)2(DABCO)0.5]·2DMA (M = Zn (2), Co (3); H2EtBCP = O-ethyl-P-(4-carboxyphenyl)phosphonic acid,…