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Time-resolved studies of chlorosilylene, ClSiH, generated by the 193 nm laser flash photolysis of 1-chloro-1-silacyclopent-3-ene, have been carried out to obtain rate constants for its bimolecular(More)
A kinetic isotope effect (kD/kH) of 7.4 has been found for the reaction of chlorosilylene with trimethylsilane (Me3SiD vs Me3SiH). Such a value can be accounted for by theoretical modeling, but only(More)