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Bis(fluoroisatinato)mercury(II) was synthesised from the reaction between 5-fluoroisatin (HFI) and mercury(II) acetate in methanol. Mercury(II) coordination with nitrogen atom of 5-fluoroisatin molecule was observed using the FT-IR and NMR spectra of the product. Quantum chemistry calculations for 5-fluoroisatin (HFI) and bis(fluoroisatinato)mercury(II)(More)
The equilibrium geometry, nuclear magnetic resonance (NMR) and UV-Vis analysis, and vibrational frequencies for the azo and hydrazone isomers of 1,3-dimethyl-5-(phenylazo)-6-aminouracil have been performed using density functional theory (DFT/B3LYP) method with 6-311G(d,p) basis set. A detailed interpretation of the vibrational spectra has been made on the(More)
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