Sebastian C Junggeburth

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Low-dimensional nanostructures offer a host of intriguing properties which are distinct from those of the bulk material, owing to size-confinement effects and amplified surface areas. Here, we report on the scalable, bottom-up synthesis of ultrathin coordination polymer nanosheets via surfactant-mediated synthesis and subsequent exfoliation. Layers of a(More)
Metal-organic frameworks (MOFs) are crystalline hybrid framework materials composed of inorganic metal “nodes” bridged by rigid organic linkers, thereby featuring exceptionally high surface areas and porosities. Despite the successful synthesis of a plethora of intricate framework topologies, a major objective in current MOF chemistry is the extension of(More)
The title compound, [Sb(2)(C(6)H(5))(6)(CH(3)O)(2)O]·2CH(3)OH, is the methanol disolvate of a dinuclear triphenyl-anti-mony derivative. The mol-ecule shows C(s) symmetry. The Sb-O-Sb angles cover a range from 89.65 (10)° to 102.08 (13)°. In the crystal structure, two O-H⋯O hydrogen bonds are present.
The alkaline earth nitridogermanate nitrides AE(7)[GeN(4)]N(2) (AE = Ca, Sr) have been synthesized using a Na flux technique in sealed Ta tubes. According to single-crystal X-ray diffraction the isotypic compounds crystallize in space group Pbcn (No. 60) with Z = 4, (Sr(7)[GeN(4)]N(2): a = 1152.6(2), b = 658.66(13), c = 1383.6(3) pm, V = 1050.5(4) x 10(6)(More)
CrystEngCo This journal is © The Royal Society of Chemistry 2015 Max Planck Institute for Solid State Research, Stuttgart, Germany. E-mail: b Ludwig Maximilian University (LMU), Department of Chemistry, Munich, Germany c Nanosystems Initiative Munich (NIM) & Center for Nanoscience (CeNS), Munich, Germany Department of Chemical(More)
The transfer of supramolecular templating to the realm of metal-organic frameworks opens up new avenues to the design of novel hierarchically structured materials. We demonstrate the first synthesis of mesostructured zinc imidazolates in the presence of the cationic surfactant cetyltrimethylammonium bromide (CTAB), which acts as a template giving rise to(More)
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