Theory of Unimolecular and Recombination Reactions
- R. Gilbert, Sean C. Smith
- Physics
- 1 September 1990
Introduction Elementary Transition State Theory Microscopic Rate Coefficients Practical Implementation of RRKM Theory Collisional Energy Transfer The Master Equation Conclusions.
Anatase TiO2 single crystals with a large percentage of reactive facets
This work synthesized uniform anatase TiO2 single crystals with a high percentage (47 per cent) of {001} facets using hydrofluoric acid as a morphology controlling agent and demonstrates that for fluorine-terminated surfaces this relative stability is reversed.
Unique electronic structure induced high photoreactivity of sulfur-doped graphitic C3N4.
- Gang Liu, P. Niu, Hui‐Ming Cheng
- ChemistryJournal of the American Chemical Society
- 3 August 2010
The homogeneous substitution of sulfur for lattice nitrogen and a concomitant quantum confinement effect are identified as the cause of this unique electronic structure and the excellent photoreactivity of C(3)N(4-x)S(x), which may shed light on general doping strategies for designing potentially efficient photocatalysts.
Solvothermal synthesis and photoreactivity of anatase TiO(2) nanosheets with dominant {001} facets.
The addition of 2-propanol can strengthen the stabilization effect associated with fluorine adsorption over (001) surface and thus stimulate its preferred growth, and the as-prepared anatase TiO(2) single-crystal nanosheets having 64% {001} facets show superior photoreactivity compared to P25 as a benchmarking material.
The 2.1A crystal structure of the far-red fluorescent protein HcRed: inherent conformational flexibility of the chromophore.
- P. Wilmann, J. Petersen, J. Rossjohn
- Chemistry, BiologyJournal of Molecular Biology
- 27 May 2005
Unimolecular Reaction Dynamics
- Sean C. Smith
- Chemistry
- 15 April 2002
Multifunctional porous graphene for nanoelectronics and hydrogen storage: new properties revealed by first principle calculations.
- A. Du, Zhonghua Zhu, Sean C. Smith
- PhysicsJournal of the American Chemical Society
- 15 February 2010
D density functional calculations are used to demonstrate for the first time that porosity such as evidenced in recently synthesized porous graphene opens a band gap, uncovering new potential for the practical application of porous graphene in nanoelectronics and clean energy.
Nanosized anatase TiO2 single crystals for enhanced photocatalytic activity.
- Gang Liu, Chenghua Sun, Hui‐Ming Cheng
- ChemistryChemical Communications
- 19 January 2010
Nanosized anatase TiO(2) single crystals with 18% {001} facets have a raised conduction band minimum by 0.1 eV, and exhibit photocatalytic activity both for generating *OH radicals and for splitting…
Phosphorene: Fabrication, Properties, and Applications.
- L. Kou, Changfeng Chen, Sean C. Smith
- ChemistryJournal of Physical Chemistry Letters
- 18 June 2015
This Perspective highlights the intrinsically anisotropic electronic, transport, optoelectronic, thermoelectric, and mechanical properties of phosphorene resulting from its puckered structure in contrast to those of graphene and transition-metal dichalcogenides.
Hybrid graphene and graphitic carbon nitride nanocomposite: gap opening, electron-hole puddle, interfacial charge transfer, and enhanced visible light response.
- A. Du, S. Sanvito, Sean C. Smith
- PhysicsJournal of the American Chemical Society
- 27 February 2012
An inhomogeneous planar substrate (g-C(3)N(4)) promotes electron-rich and hole-rich regions, i.e., forming a well-defined electron-hole puddle, on the supported graphene layer, which can potentially allow overcoming the graphene's band gap hurdle in constructing field effect transistors.
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