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The title compound, C 48 H 43 N 7 , is a polyazapolycyclic compound with a near-C 2 symmetric skeleton. In the crystal, a N—HÁ Á Á interaction occurs.
In the title compound, C(34)H(31)N(5), the observed molecular geometry suggests that anomeric effects are present in terms of short C-N bond lengths and reduced pyramidality of the N atoms.
A new member of the polyazapolycyclic family of compounds, namely N(3),N(6),2,5,7-pentaphenyl-2,5,7-triazabicyclo[2.2.1]heptane-3,6-diamine xylene solvate, C(34)H(31)N(5).C(8)H(10), was synthesized for the first time and the crystal structure is reported. There are no hydrogen bonds joining the molecules. All four chiral C atoms have the same absolute… (More)