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Journals and Conferences
Stearates containing overbased detergent nanoparticles (NPs) are used as acid neutralising additives in automotive and marine engine oils. Molecular dynamics (MD) simulations of the self-assembly of calcium carbonate, calcium stearate as a co-surfactant and stabilising surfactants of such NPs in a model explicit molecular hydrophobic solvent have been… (More)
The solvent control on the ability of a partially substituted lower rim calix(4)arene derivative 5,11,17,23,tetra-tert-butyl[25,27-bis(hydroxy)-26,28-bis(ethylthioethoxy)]-calix(4)arene, 1 to host soft metal cations (Hg(II) and Ag(I)) is demonstrated through 1H NMR, electrochemical (conductance measurements), and thermodynamic characterization of the… (More)
The solid state interaction of mono and macromolecular thiols at a disulfide heterocycle is shown to provide a versatile pathway for their speciation.
An additive thermodynamic contribution of pendant arms to the complexation of calixarene derivatives with mercury(II) in acetonitrile is for the first time demonstrated.
The interaction of lower rim calix(4)arene derivatives containing ester (1) and ketone (2) functional groups and bivalent (alkaline-earth, transition- and heavy-metal) cations has been investigated in various solvents (methanol, N,N-dimethylformamide, acetonitrile, and benzonitrile). Thus, 1H NMR studies in CD3OD, C3D7NO, and CD3CN show that the interaction… (More)
This paper reports thermodynamic data for the transfer of calixarene derivatives and their metal-ion complexes in dipolar aprotic solvents. These data are used to assess the effect of solvation of these compounds on the selective complexation shown by these macrocycles for soft metal cations in different media. Thus, solubilities and derived Gibbs energies… (More)