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Stereoselective Total Synthesis of (+/-)-Swainsonine Based on Endo Mode Cyclization.
- C. Mukai, Yu-ichi Sugimoto Yi, K. Miyazawa, S. Yamaguchi, M. Hanaoka
- Chemistry, Medicine
- The Journal of organic chemistry
- 8 August 1998
A new stereoselective total synthesis of (+/-)-swainsonine is described. Successive treatment of cis-3,4-epoxy-7-(p-toluenesulfonamido)-1-heptyne with dicobalt octacarbonyl, Lewis acid, and… Expand
Co2(CO)8-mediated endo mode cyclization of epoxy-alcohol: synthesis of 2-ethynyl-3-hydroxy-2-methyltetrahydropyran and 2-ethynyl-3-hydroxy-3-methyltetrahydropyran derivatives.
- C. Mukai, S. Yamaguchi, I. J. Kim, M. Hanaoka
- Chemistry, Medicine
- Chemical & pharmaceutical bulletin
- 1 May 2001
Successive treatment of 4,5-epoxy-5-methyl-7-trimethylsilyl-6-heptyne-1-ol with Co2(CO)8 at 0 degrees C and a catalytic amount of BF3 x OEt2 at -78 degrees C gave the tetrahydropyran derivatives with… Expand
Co2(CO)8‐Mediated endo Mode Cyclization of Epoxy‐Alcohol: Synthesis of 2‐Ethynyl‐3‐hydroxy‐2‐methyltetrahydropyran and 2‐Ethynyl‐3‐hydroxy‐3‐methyltetrahydropyran Derivatives.
N-alkoxyalkyl-N, N-dialkylamine derivatives or their salts and degenerative diseases medicinals for the treatment of nervous containing them
N-alkoxyalkyl derivatives -n, n-dialkylamine or salts thereof and agents for treating neurodegenerative diseases comprising the same.
Un derivado de N-alcoxialquil-N,N-dialquilamina representado por la siguiente formula general, o su sal: ** ver formula** en la que R 1 y R 2 son iguales o diferentes y representan al menos un grupo… Expand
N-alkoxyalkyl-n,n-dialkylamine derivatives or salts thereof, and agents for treating neurodegenerative diseases comprising the same
N-Alkoxyalkyl-N,N-dialkylamine derivatives of general formula  or salts thereof, which exhibit antihypoxic, nerve protecting and nerve regeneration promoting effects and are useful as remedies for… Expand
N-alkoxylkyl-N, N-dialkylamine derivatives or salts thereof and agents for neurodegenerative diseases containing these
Endo Mode Cyclization of 5,6-Epoxy-7-octyn-1-ol Derivatives.