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Syntheses, Structures, Solution, and Solid-State 27Al NMR Studies of Blue Luminescent Mononuclear Aluminum Complexes: Al(7-azain)2(7-azain-H)(CH3), Al(7-azain)3(7-azain-H), and
Three novel mononuclear aluminum complexes, Al(7-azain)2(7-azain-H)(CH3) (1), Al(7-azain)3(7-azain-H) (2), and Al(7-azain)(7-azain-H)(OCH(CF3)2)2 (3), where 7-azain-H = 7-azaindole, have beenExpand
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Organobismuth(V) complexes containing bifunctional ligands:hydrogen-bonded extended structures and stereoselectivity
New bismuth(V) complexes with the general formula of Bi V R 3 (O 2 CR′) 2 have been synthesized by the reaction of BiR 3 Cl 2 with Ag(O 2 CR′), where R is an aromatic ligandExpand
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Impact of donor-acceptor geometry and metal chelation on photophysical properties and applications of triarylboranes.
Three-coordinate organoboron compounds have recently found a wide range of applications in materials chemistry as nonlinear optical materials, chemical sensors, and emitters for organicExpand
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Luminescence and electroluminescence of Al(III), B(III), Be(II) and Zn(II) complexes with nitrogen donors
Abstract Blue luminescent complexes of aluminum(III), boron(III), beryllium(II) and zinc(II) using ligands that contain only nitrogen donor atoms are presented. The ligands in these complexes areExpand
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(1-Naphthyl)phenylamino functionalized three-coordinate organoboron compounds: syntheses, structures, and applications in OLEDs
New three-coordinate organoboron compounds functionalized by a (1-naphthyl)phenylamino group, B(mes)2(dbp-NPB) (1), B(db-NPB)3 (2), and B(dbp-NPB)3 (3), have been synthesized. A variableExpand
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Phosphorescent Cu(I) complexes of 2-(2'-pyridylbenzimidazolyl)benzene: impact of phosphine ancillary ligands on electronic and photophysical properties of the Cu(I) complexes.
Four mononuclear Cu(I) complexes of 2-(2'-pyridyl)benzimidazolylbenzene (pbb) with four different ancillary phosphine ligands PPh(3), bis[2-(diphenylphosphino)phenyl]ether (DPEphos),Expand
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Formation of azaborines by photoelimination of B,N-heterocyclic compounds.
Highly fluorescent π-conjugated polycyclic azaborines can be prepared from B,N-heterocyclic compounds with a BR2 -CH2 unit through the elimination of an R-H molecule (see scheme). These cleanExpand
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Bluish-green BMes2-functionalized Pt(II) complexes for high efficiency PhOLEDs: impact of the BMes2 location on emission color.
New phosphorescent Pt(II) compounds based on dimesitylboron (BMes(2))-functionalized 2-phenylpyridyl (ppy) N,C-chelate ligands and an acetylacetonato ancillary ligand have been achieved. We haveExpand
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G-quartet formation from an N2-modified guanosine derivative.
[structure: see text] We report G-quartet formation from an N2-modified lipophilic guanosine nucleoside, N2-(4-n-butylphenyl)-2',3',5'-O-triacetylguanosine. We show that, in the presence of either K+Expand
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