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Oxo- and hydroxo-bridged diiron(III) porphyrin dimers: Inorganic and bio-inorganic perspectives and effects of intermacrocyclic interactions
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Hydrogen-Bonding Interactions Trigger a Spin-Flip in Iron(III) Porphyrin Complexes**
TLDR
This study highlights the possible effects and importance of hydrogen-bonding interactions in heme proteins and is the first example of a synthetic iron(III) complex that can reversibly change its spin state between a high and an intermediate state through weak external perturbations.
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Syn–anti conformational switching: Synthesis and X-ray structures of tweezer and anti form in a zinc porphyrin dimer induced by axial ligands
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Induction of supramolecular chirality in di-zinc(II) bisporphyrin via tweezer formation: synthesis, structure and rationalization of chirality.
TLDR
X-ray structure and other spectroscopic investigations of the tweezer complexes clearly rationalize the origin of the optical activity that has so far remained an unresolved issue.
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Cyclic metalloporphyrin dimers: Conformational flexibility, applications and future prospects
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Hydrogen-Bonding Interactions Trigger a Spin-Flip in Iron(III) Porphyrin Complexes**
TLDR
This study highlights the possible effects and importance of hydrogen-bonding interactions in heme proteins and is the first example of a synthetic iron(III) complex that can reversibly change its spin state between a high and an intermediate state through weak external perturbations.
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A Family of (N-Salicylidene-α-amino acidato)vanadate Esters Incorporating Chelated Propane-1,3-diol and Glycerol: Synthesis, Structure, and Reaction
The brown colored title complexes, VVO(Asal)(Hpd) and VVO(Asal)(H2pt), have been synthesized in excellent yields by reacting VIVO(Asal)(H2O) with propane-1,3-diol (H2pd) and glycerol (H3pt),…
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Synthesis, structure and metal redox of alkoxide bound oxovanadium(V) complexes incorporating N-salicylidene/N-naphthalidene-α-aminoalcohols
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Ruthenium dithiophosphates: synthesis, X-ray crystal structure, spectroscopic and electrochemical properties
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Pyramidalization of Gd3N inside a C80 cage. The synthesis and structure of Gd3N@C80.
The X-ray crystal structure of Gd(3)N@C(80).Ni(II)(OEP).1.5(benzene) shows that the Gd(3)N unit within the I(h) C(80) cage is pyramidal, whereas Sc(3)N@C(80), Sc(3)N@C(78), Sc(3)N@C(68), Lu(3)N@C(80)…
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