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Catalytic Cyanomethylation of Carbonyl Compounds and Imines with Highly Basic Phosphine.
P-CHIRAL BIS(TRIALKYLPHOSPHINE) LIGANDS AND THEIR USE IN HIGHLY ENANTIOSELECTIVE HYDROGENATION REACTIONS
Asymmetric Catalytic Aldol-type Reaction with Ketene Silyl Acetals: Possible Intervention of the Silatropic Ene Pathway
Asymmetric catalysis of carbonyl-ene and aldol reactions with fluoral by chiral binaphthol-derived titanium complex
Abstract The chiral titanium complex-catalyzed ene-type reaction and the Mukaiyama aldol reaction with fluoral are shown to serve as an efficient route to the enantioselective and diastercoselective… Expand
Catalytic cyanomethylation of carbonyl compounds and imines with highly basic phosphine
Abstract A highly basic phosphine, tris(2,4,6-trimethoxy phenyl)phosphine (TTMPP), catalyzes cyanomethylation using trimethylsilylacetonitrile (TMSCH 2 CN) to give the corresponding products in good… Expand
SELF-ASSEMBLY OF SEVERAL COMPONENTS INTO A HIGHLY ENANTIOSELECTIVE TI CATALYST FOR CARBONYL-ENE REACTIONS
Synthesis of P-chirogenic diphosphine oxides and their use in catalytic asymmetric Diels–Alder reaction
Abstract New P-chirogenic phosphine oxides, ( R , R )-1,2-bis(alkylmethylphosphinyl)ethanes (alkyl=1-adamantyl, tert -butyl) and ( S , S )-1,1-bis( tert -butylmethylphosphinyl)methane have been… Expand
Tandem and two-directional asymmetric catalysis of the Mukaiyama aldol reaction
Abstract Upon addition of an excess amount of an aldehyde 3, the Mukaiyama aldol reaction of a silyl enol ether 2 proceeds in tandem and two-directional fashion by the asymmetric catalysis of a… Expand
Asymmetric Catalysis of the Mukaiyama Aldol Reaction with Fluoral: A Highly Enantioselective Access to Fluorine-containing Aldols
TBD-Catalyzed Trifluoromethylation of Carbonyl Compounds with (Trifluoromethyl)trimethylsilane
Abstract Trifluoromethylation of carbonyl compounds using (trifluoromethyl) trimethylsilane catalyzed by 1,5,7-triazabicyclo[4,4,0]dec-5-ene (TBD) afforded the corresponding α-trifluoromethyl… Expand