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Functional porous coordination polymers.
The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Soft porous crystals.
The concept of the cooperative integration of 'softness' and 'regularity' and the relationship between the structures and properties of these materials in view of their practical applications are discussed.
Nanoporous nanorods fabricated by coordination modulation and oriented attachment growth.
- T. Tsuruoka, S. Furukawa, Y. Takashima, Kaname Yoshida, S. Isoda, S. Kitagawa
- Materials ScienceAngewandte Chemie
- 15 June 2009
Investigation of the crystal growth mechanism by TEM indicates that face-selective modulation on the surfaces of PCP crystals enhances the anisotropic crystal growth of nanorods by an oriented attachment mechanism.
Selective sorption of oxygen and nitric oxide by an electron-donating flexible porous coordination polymer
The effective selective sorption of dioxygen and nitric oxide is described by a structurally and electronically dynamic porous coordination polymer built from zinc centres and tetracyanoquinodimethane (TCNQ) as a linker.
Prussian blue nanoparticles protected by poly(vinylpyrrolidone).
Measurement of the critical temperature where PB nanoparticles exhibit a ferromagnetic property showed a gradual decrease of Tc for the nanoparticles as the particle sizes become smaller, which could be ascribed to the reduction of the averaged numbers of magnetic interacted neighbors.
Formation of a One-Dimensional Array of Oxygen in a Microporous Metal-Organic Solid
We report the direct observation of dioxygen molecules physisorbed in the nanochannels of a microporous copper coordination polymer by the MEM (maximum entropy method)/Rietveld method, using in situ…
A pillared-bilayer porous coordination polymer with a 1D channel and a 2D interlayer space, showing unique gas and vapor sorption.
- Prakash Kanoo, G. Mostafa, R. Matsuda, S. Kitagawa, T. Maji
- Physics, Materials ScienceChemical communications
- 5 July 2011
A new 2D pillared-bilayer porous coordination polymer (PCP) has been synthesized and structurally characterized that shows selective adsorption of CO(2) over other gases (N(2), O(2), Ar, H(2), CH(4))…
Terminology of metal–organic frameworks and coordination polymers (IUPAC Recommendations 2013)
A set of terms, definitions, and recommendations is provided for use in the classification of coordination polymers, networks, and metal–organic frameworks (MOFs). A hierarchical terminology is…
Dynamic porous properties of coordination polymers inspired by hydrogen bonds.
This tutorial review focuses on the hydrogen bonding type arrangements for dynamic porous coordination polymers exhibiting elastic guest accommodations, in contrast to rigid three-dimensional (3-D) frameworks.
Direct carbonization of Al-based porous coordination polymer for synthesis of nanoporous carbon.
- Ming Hu, J. Reboul, Y. Yamauchi
- Materials Science, ChemistryJournal of the American Chemical Society
- 1 February 2012
Nanoporous carbon shows much higher porosity than other carbon materials (such as activated carbons and mesoporous carbons) and exhibits superior sensing capabilities toward toxic aromatic substances.