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Reactions of Amine- and Phosphane-Borane Adducts with Frustrated Lewis Pair Combinations of Group 14 Triflates and Sterically Hindered Nitrogen Bases
The ability of trialkyl Group 14 triflates in combination with amine and pyridine bases to dehydrogenate amine- and phosphane―borane adducts has been investigated. By using multinuclear NMRExpand
Photocontrolled living anionic polymerization of phosphorus-bridged [1]ferrocenophanes: a route to well-defined polyferrocenylphosphine (PFP) homopolymers and block copolymers.
The living nature of the photocontrolled anionic ROP allowed the synthesis of well-defined all-organometallic PFP-b-PFS(F) diblock copolymers through sequential monomer addition. Expand
Synthesis, Structure, Electrochemical, and Spectroscopic Properties of Hetero-Bimetallic Ru(II)/Fe(II)-Alkynyl Organometallic Complexes.
The redox and NIR absorption features indicate that the mixed-valence system of the heterobinuclear dyads belongs to a Robin and Day "class II" system and two well-separated reversible redox waves as a result of successive oxidation of the ferrocenyl and Ru(II) redox centers. Expand
Cylindrical micelles of controlled length with a π-conjugated polythiophene core via crystallization-driven self-assembly.
Solution self-assembly of the regioregular polythiophene-based block copolymer poly(3-hexylthiophene)-b-poly(dimethylsiloxane) yields cylindrical micelles with a crystalline P3HT core. MonodisperseExpand
Main-chain heterobimetallic block copolymers: synthesis and self-assembly of polyferrocenylsilane-b-poly(cobaltoceniumethylene).
Main-chain heterometallic block copolymers composed of iron- and cobalt-rich blocks were synthesized through consecutive photocontrolled ring-opening polymerization of sila and dicarba followed by oxidation of the cobaltocene-containing block. Expand
Dimensional control of block copolymer nanofibers with a π-conjugated core: crystallization-driven solution self-assembly of amphiphilic poly(3-hexylthiophene)-b-poly(2-vinylpyridine).
The crystallinity and π-conjugated nature of the P3HT core in the fiberlike micelles was confirmed by a combination of UV/Vis spectroscopy, photoluminescence (PL) measurements, and wide-angle X-ray scattering (WAXS). Expand
Fiber-like Micelles via the Crystallization-Driven Solution Self-Assembly of Poly(3-hexylthiophene)-block-Poly(methyl methacrylate) Copolymers
The solution self-assembly of block copolymers with a π-conjugated, crystalline, core-forming block represents a facile strategy toward the preparation of semiconducting nanowires with potential forExpand
A highly selective, sensitive and reusable BODIPY based ‘OFF/ON' fluorescence chemosensor for the detection of Hg2+ Ions
Abstract A BODIPY (borondipyrromethane) based fluorescence probe anchored with N,N-bis(2-(pyridin-2-ylmethoxy)ethyl)aniline receptor (BDPS) has been designed, synthesized and successfullyExpand
Role of axial donors in the ligand isomerization processes of quadruply bonded dimolybdenum(II) compounds.
The mechanism involving acetate migration through axial coordination has been invoked to rationalize the product formation and the ligand arrangements observed in the solid state are mostly retained in the acetonitrile medium. Expand
Effects of axial coordination on the Ru-Ru single bond in diruthenium paddlewheel complexes.
The 1,8-naphthyridine-based (NP-based) ligands with furyl, thiazolyl, pyridyl, and pyrrolyl attachments at the 2-position have been synthesized and DFT calculations provide insight into the interaction of the Ru-Ru sigma orbital with axial donors. Expand