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The Kinetics of Electron Transfer Through Ferrocene-Terminated Alkanethiol Monolayers on Gold
The kinetics of electron transfer between a substrate gold electrode and a self-assembled monolayer formed from CH{sub 3}(CH{sub 2}){sub n-1}SH and ({eta}{sup 5} C{sub 5}H{sub 5})Fe ({eta}{supExpand
Electrostatic interactions among hydrophobic ions in lipid bilayer membranes.
We have shown that the absorption of tetraphenylborate into black lipid membranes formed from either bacterial phosphatidylethanolamine or glycerolmonooleate produces concentration-dependent changesExpand
Heterogeneous electron-transfer kinetics for ruthenium and ferrocene redox moieties through alkanethiol monolayers on gold.
The standard heterogeneous electron-transfer rate constants between substrate gold electrodes and either ferrocene or pentaaminepyridine ruthenium redox couples attached to the electrode surface byExpand
AN INDIRECT LASER-INDUCED TEMPERATURE JUMP DETERMINATION OF THE SURFACE PKA OF 11-MERCAPTOUNDECANOIC ACID MONOLAYERS SELF-ASSEMBLED ON GOLD
The indirect laser-induced temperature jump (ILIT) method is used to determine the acidity (pKa) of monolayers composed of 11-mercaptoundecanoic acid (MUA) self-assembled on vapor-deposited gold filmExpand
Distance dependence of heterogeneous electron transfer through the nonadiabatic and adiabatic regimes
Abstract The Landau–Zener formalism, which is strictly valid for a two-state system, is extended to multistate systems by assuming that the electronic interaction between the redox moiety and a givenExpand
Reinterpretation of polypyrrole electrochemistry. Consideration of capacitive currents in redox switching of conducting polymers
A simple analysis of the capacitive currents associated with the electrochemical (cyclic voltammetric) switching of a polypyrrole film between its reduced (insulating) and oxidized (electronicallyExpand
Current Rectification at Quartz Nanopipet Electrodes
Ag/AgCl reference electrodes fabricated from pulled quartz tubes with orifice radii of 20 nm to 20 μm were characterized in KCl solutions of different concentrations by cyclic voltammetry. LinearExpand
Quantized Capacitance Charging of Monolayer-Protected Au Clusters
A theoretical model based on electrostatic interactions is developed to account for the formal potentials of current peaks observed in differential pulse voltammetry of solutions of 10 differentExpand
Electrochemical Measurements of Single H2 Nanobubble Nucleation and Stability at Pt Nanoelectrodes.
TLDR
Single H2 nanobubble nucleation is studied at Pt nanodisk electrodes of radii less than 50 nm, where H2 is produced through electrochemical reduction of protons in a strong acid solution and the effects of different surfactants are consistent with the classic nucleation theory. Expand
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