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Asymmetric synthesis of diarylmethylamines with high enantioselectivity (95-99% ee) was realized by use of a new C2-symmetric diene ligand, (1R,4R)-2,5-diphenylbicyclo[2.2.2]octa-2,5-diene (Ph-bod*),(More)
A palladium-catalyzed asymmetric decarboxylative reaction of racemic gamma-methylidene-delta-valerolactones with aryl isocyanates has been developed to give enantioenriched 3,3-disubstituted(More)