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Abstract Nine mononuclear metal complexes of monoanionic α-hydroxycarboxylates (HL′) with imidazole as a co-ligand have been synthesised and structurally characterized by X-ray diffraction. The(More)
Reaction of group 12 metal dihalides in ethanolic media with 2-acetylpyridine 4N-phenylthiosemicarbazone (H4PL) and 2-acetylpyridine-N-oxide 4N-phenylthiosemicarbazone (H4PLO) afforded the compounds(More)
Abstract The 1D coordination polymer 1∞[Cu(HL)2(SS)]·4H2O (1) and the molecular compound [Cu2(HL)4(SCS)3] (2) [where SS = 4,4′-dipyridyldisulfide, SCS = bis(4-pyridylthio)methane and HL = lactate](More)
Abstract Four hydrogen-bonded assemblies of formula [M(dpds) 2 (OH 2 ) 2 ]A 2 · n H 2 O (A = anion) are described. These assemblies result from the second-sphere coordination interactions between the(More)
Five new complexes, [Cu(L1)2(SS)2] (1), [Cu(L1)2(SS)2]·H2O (1w1), [Cu2(L1)2(SCS)]·H2O (2w1), 1∞[Cu(L2)2(SS)]·4H2O (3w1D), and 2∞[Cu(L2)2(SCS)]·2H2O (4w1D) (where SS = 4,4′-dipyridyldisulfide, SCS =(More)
Five coordination polymers 1 {[Cu4(HCO2)6(OH)2(4dpds)2]·2CH2Cl2}n, 2 {[Cu4(CH3CO2)6(OH)2(4dpds)2]}n, 3 {[Cu(4dpds)2(H2O)2](4pySO3)2·2H2O}n, 4 {[Cu(4pySO3)2(4dpds)2]·2H2O}n and 5(More)